Ocean “Acidification” — Another Fake Scare That Won’t Go Away

From THE MANHATTAN CONTRARIAN

Francis Menton

Ocean “acidification” is a somewhat unique branch of the overarching climate scare. It differs from other branches of the big scare in that it does not depend on atmospheric heating as the driver of the supposed scary consequences. Instead, with ocean “acidification,” the idea is that increased CO2 in the atmosphere (from the burning of fossil fuels) leads to increased CO2 dissolved in the oceans, which leads to lower pH of ocean water, which then becomes the driver of the alleged scary consequences. Thus, ocean “acidification” can theoretically work as a scare even if the atmosphere fails to heat with increasing CO2 content to the extent predicted by advocates’ climate models.

But the ocean “acidification” claim has its own frailties. For advocates of apocalyse, it is a problem that the ocean is (somewhat) alkaline, rather than acidic, and that the change in ocean pH from even large increases in CO2 in the atmosphere is small. Some might even call the change in ocean pH “slight.” And the pH change, even in worst-case scenarios, is not nearly enough to bring it down to the level of neutrality, let alone acidity. The last point is the reason that I have been putting the term “acidification” in quotes.

So, how can advocates make ocean “acidification” into something sufficiently scary to motivate lots of people to hate or fear fossil fuels? Well, perhaps they could manufacture a claim that somewhat lower pH would kill all the tropical fish. OK, but the claim could not be that slightly lower pH will directly kill the fish — nobody would ever buy that. There would have to be a different mechanism.

Several years ago (May 2021) I had a post covering the work of a pair of researchers in Australia who had come up with a claim fitting just this description. The researchers in question were Philip Munday and Danielle Dixson of James Cook University in Queensland. Over the course of multiple years and some 22 peer-reviewed papers, those two (and co-authors) had put forth a claim that lower ocean pH would drive tropical fish crazy, or at least cause the fish to experience “profound behavioral and sensory impairments” that would imperil their survival. As should be obvious, this claim gave extraordinary support to the anti-fossil fuel narrative, independent of any claim of global warming, and as a result gave the papers a very high profile, and brought the authors great acclaim.

But it was too good to be true. The occasion for my May 2021 post was a paper that had appeared in Nature in 2020, by authors Timothy Clark, et al., reporting on the results of efforts to reproduce the Munday/Dixson results. Excerpt from the abstract:

Here, we comprehensively and transparently show that—in contrast to previous studies—end-of-century ocean acidification levels have negligible effects on important behaviours of coral reef fishes, such as the avoidance of chemical cues from predators, fish activity levels and behavioural lateralization (left–right turning preference). Using data simulations, we additionally show that the large effect sizes and small within-group variances that have been reported in several previous studies are highly improbable. Together, our findings indicate that the reported effects of ocean acidification on the behaviour of coral reef fishes are not reproducible, suggesting that behavioural perturbations will not be a major consequence for coral reef fishes in high CO2 oceans.

The abstract does not contain the word “fraud,” but the article contains strong suggestions of data manipulation. This was a very unusual piece for Nature to publish, given the harm it caused to a significant underpinning of the anti-fossil fuel narrative.

Here we are now, five years on. Does anything remain of the “ocean acidification” narrative as a reason to hate fossil fuels?

The past few months have seen pieces laying out the cases both for and against believing that “ocean acidification” is a significant environmental concern. On the side of “ocean acidification is really bad and scary,” I will highlight a piece by Dana Nuccitelli that appeared in something called The Invading Sea in March, title “Fossil fuel pollution’s effect on oceans comes with huge costs.” On the side of “ocean acidification is way overblown,” I will highlight a May 13, 2026 paper by van Wijngaarden, Ridd, Cornell and Happer, title “Acidification of Water by CO2.”

Nuccitelli is a frequent writer at Yale Climate Connections (yet another black eye for Yale). In Nuccitelli’s piece, he appears to have given up on trying to claim that changing pH is killing off the tropical fish. So instead, here, he emphasizes the effect on coral. He claims that “acidification” is killing off coral, but can’t attribute dying coral just to pH, so he throws in warming as well:

Florida’s barrier reef is in trouble – and it’s costing us. The reef has been experiencing a severe outbreak of stony coral tissue loss disease over the past decade. The likely cause: stress from the warming climate and acidifying waters, both the result of burning fossil fuels. . . . Human burning of fossil fuels affects Earth’s oceans via the one-two punch of warming and acidifying waters, which occurs as carbon dioxide is absorbed into the ocean.

No quantitative information is provided for the amount of coral loss, if any. The “likely cause” of the disease is said to be a combination of “warming” and “acidifying waters.” How does he know that? How much from each? Is there any actual proof? If so, Nuccitelli does not choose to cite it. I guess it’s just obvious to his readership.

After asserting the “likely cause,” Nuccitelli moves on to calculating the cost, not of the portion of the coral that may be lost, but of the entire tourism industry related to all the coral:

The financial stake of losing the reef is high. Florida’s coral reefs are estimated to draw in over $1 billion in tourism revenue each year, provide $650 million in flood protection benefits and support over 70,000 jobs. What’s more, coral reefs protect people and property by dissipating up to 97% of wave energy, lessening storm surges.

And then Nuccitelli goes on to rely on a recent paper from Nature Climate Change (from January 2026) that purports to calculate a new measure of “social cost of carbon” on an assumption that global warming will significantly decrease the productivity of the oceans, not just for coral, but all other life. The NCC paper does not appear to deal with the acidification issue at all.

Here’s my favorite chart from Nuccitelli’s article on the subject of “acidification”:

It looks like the ocean pH is dropping like a stone! Do you notice anything odd? The entire vertical scale of the chart goes from pH of 8.03 to 8.11 — less than 0.1 of a pH unit. The full pH scale goes from 0 to 14. If you plotted this line with a vertical scale going all the way from 0 to 14, the line would be indistinguishable from horizontal.

If you are interested in the question of whether ocean corals are increasing or decreasing around the world, I can recommend several pieces to you from Peter Ridd. Ridd is a guy who actually goes out and studies the corals (he was formerly at James Cook University, like Munday and Dixson, until he got thrown out for heresy). He is also the same Ridd who is a co-author on the van Wijngaarden, et al., paper further discussed below. Here is a piece Ridd wrote in 2023 for the Global Warming Policy Foundation called “Coral in a Warming World, Causes for Optimism”; and here is one from August 2025 from the Institute of Public Affairs, title “Science group think flounders on state of Great Barrier Reef.” The bottom line is that there is plenty of evidence that coral reefs worldwide are thriving (not every one, and not every year, but on an aggregate basis), and no evidence at all of aggregate decline. In light of that evidence, what is the proof that “acidification” is harming corals? The answer is, zero.

In contrast to Nuccitelli’s evidence-free advocacy piece, the van Wijngaarden, et al., paper is a serious piece of scientific work. I note that it appears on the website of the CO2 Coalition, rather than in one of the “prestige” scientific journals. I infer that these authors, who actually are the best scientists to address this topic, have given up on the enforced groupthink of these “prestige” magazines.

The paper is long (55 pages), and much of it is technical. But the bottom line is that it is preposterous to believe that the slight decline in ocean pH caused by increased atmospheric CO2 can cause any significant problem for ocean life. In this blog post, I will only provide a summary quote. From the Abstract:

Fundamental inorganic chemistry shows that increasing concentrations of atmospheric CO2 will have no harmful effect on organisms that live in the natural waters of the Earth [1], and may well benefit them. Alkalinity and dissolved CO2 give high buffering capacity to most natural waters and minimize the change of pH from external influences. For example, doubling the atmospheric concentration of CO2 from 430 ppm to 860 ppm would reduce the pH of representative sea water at a temperature of 25 C from pH = 8.18 to pH = 7.93. This change is comparable to diurnal pH changes in biologically productive surface waters, due to photosynthetic fixation of dissolved inorganic carbon during the day and respiration at night. The change is also less than the variations of pH with latitude, longitude and depth in the oceans.

A key point is that the pH of the ocean is not a fixed number for the whole world at a given point in time. Rather, pH varies within small ranges based on latitude, longitude, depth, and even time of day. The result is that ocean life already has to deal with these ranges.

A big part of the paper deals with the chemistry of how much the pH of the ocean might be affected by increase in atmospheric level of CO2 from the current 430 ppm up to even a doubling of same to 860 pm. Some mathematics is involved, but I think it is basic and well-known chemistry. The conclusion, as stated in the abstract, is that the average pH could go down all the way to 7.93 — still well into the alkaline range (neutral is 7, alkaline above 7, and acid below 7).

If anyone is aware of research establishing that pH variation in the ranges indicated are some kind of grave threat to ocean life, I would be eager to be made aware of it. Until I see that, my conclusion is that the whole “ocean acidification” thing is no more than an effort to play on the idea that people will find the word “acid” scary.

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137 Comments
migueldelrio
May 30, 2026 10:21 am

Ignorance of basic chemistry is one excuse for not recognizing that the ratio of dissolved aqueous CO2 to carbonic acid in seawater is 1000 to one:

“Although the concentration of CO2(aq) far exceeds that of dissolved H2CO3 (in the order of 10³) we denote the concentration of all dissolved CO2 by [H2CO3]”- from section 9.2 of CHEMISTRY OF CARBONIC ACID IN WATER, https://web.archive.org/web/20260424102315/https://www.scribd.com/doc/73716594/cht-i-09

To my knowledge, all modern climate change texts that reference ocean acidification omit the units when quoting the equations.

(Search for “although,” which is on page 2, to avoid the paywall. Note also that “10³” was replaced by “103” when the PDF formatting was stripped. The original PDF document was removed from the IAEA site, www-naweb.iaea.org, though the document survives in this form.)

migueldelrio
Reply to  migueldelrio
May 30, 2026 10:50 am

The paywalled version of section 9.2 of CHEMISTRY OF CARBONIC ACID IN WATER has the original tables and graphs. You can view some ads or pay the fee to review all 24 pages here: https://www.scribd.com/doc/73716594/cht-i-09

migueldelrio
Reply to  migueldelrio
May 30, 2026 11:11 am

Special thanks to user almutaz9879 for uploading this valuable document to scribd.com.

migueldelrio
Reply to  migueldelrio
May 30, 2026 2:33 pm

Compared the 2015/03/31 version of cht_i_09.pdf on my hard drive with the version I downloaded today from Scribd.com. Page-by-page comparison revealed no differences, though the Scribd.com version is more than twice the size.

migueldelrio
Reply to  migueldelrio
May 30, 2026 12:11 pm

The paper, Foraminiferal boron isotope ratios as a proxy for surface ocean pH over the past 21 Myr, provides evidence that ocean alkalinity is near a record high: https://www.nature.com/articles/363149a0

Reply to  migueldelrio
May 30, 2026 2:26 pm

that ocean alkalinity is near a record high:”

That is also suggested by the Flinder’s Reef data when compared to the Aloha data. (see graph elsewhere).. but on a much shorter time scale.

migueldelrio
Reply to  bnice2000
May 30, 2026 6:55 pm

Yes, in 2015, the big climate concern was that the “average global” pH dropped from 8.00 to 7.99. Of course, the question that was then raised was, “Where exactly is this mean (so that we may reproduce the experiment)?”

migueldelrio
Reply to  bnice2000
May 30, 2026 7:42 pm

Mollusks can survive at pH 4.7 in the wild near sulfur vents, according to Google AI, which managed to break the paywall to Survival of mussels in extremely acidic waters on a submarine volcano (https://www.nature.com/articles/ngeo500), utilizing photosynthesis to precipitate shells in such low-pH conditions. Ergo, the ocean acidification is hype.

migueldelrio
Reply to  bnice2000
May 30, 2026 9:46 pm

Here’s the transcript for ‘Mollusks can survive at pH 4.7 in the wild near sulfur vents,’ https://www.google.com/search?q=Mollusks+can+survive+at+pH+4.7+in+the+wild+near+sulfur+vents.&sourceid=chrome&ie=UTF-8

Yes, specific deep-sea mollusks endure extreme conditions, including pH levels as low as 4.7, by relying on unique chemosynthetic bacteria to process toxic vent chemicals into food instead of sunlight.

Vent Mussels: Dense clusters of the mussel Bathymodiolus brevior have been observed living in highly acidic waters ranging from pH 5.36 down to 4.7 on the northwest Eifuku volcano in the Mariana arc, where liquid carbon dioxide and hydrogen sulfide emerge.Volcano Snails: The scaly-foot snail (Chrysomallon squamiferum) lives near Indian Ocean hydrothermal vents. It survives extreme temperatures and chemical environments by hosting beneficial bacteria in an enlarged gland and reinforcing its shell with iron sulfide minerals. [1, 5, 6]Read more about their habitats and survival strategies on the NOAA PMEL or
Ocean Conservancy

sites.

AI responses may include mistakes.
[1] https://www.facebook.com/thesciencepulse/posts/scaly-foot-snails-are-deep-sea-mollusks-that-live-in-hydrothermal-vent-regions-o/1323392396498459/
[2] https://ocean.si.edu/ocean-life/invertebrates/meet-metal-snail-bottom-ocean
[3] https://www.pmel.noaa.gov/eoi/featured-publication/survival-mussels-extremely-acidic-waters-submarine-volcano
[4] https://www.pmel.noaa.gov/eoi/featured-publication/survival-mussels-extremely-acidic-waters-submarine-volcano
[5] https://nc.iucnredlist.org/redlist/resources/files/1591026714-Amazing_Species_-_Scaly-foot_Snail__Chrysomallon_squamiferum_.pdf
[6] https://www.newscientist.com/article/2388510-the-delightfully-bizarre-creatures-that-live-near-deep-sea-vents/

The Survival of mussels in extremely acidic waters on a submarine volcano indicates that chemosynthesis, rather than photosynthesis, is responsible for shell precipitation (my mistake).

Reply to  migueldelrio
June 2, 2026 9:50 pm

Calcifiers are able to manipulate the pH at the growing edge of shells, albeit with the expenditure of energy. However, once the cell is created, they use strategies such as coating the shell with mucous and/or chitin to prevent sea water from dissolving it.

migueldelrio
Reply to  migueldelrio
June 1, 2026 6:17 am

Special thanks to Miriam from Sales at the IAEA, who has posted ENVIRONMENTAL ISOTOPES IN THE HYDROLOGICAL CYCLE in its entirety. Section 9.2 on page 144, Carbonic acid equilibria, has the statement, “Although the concentration of CO2(aq) far exceeds that of dissolved H2CO3 (in the order of 10³) we denote the concentration of all dissolved CO2 by [H2CO3].” (Document page 144 is PDF page 159 due to the preface.)

If anyone knows about Carbonic acid equilibria, it is the International Atomic Energy Agency.

migueldelrio
Reply to  migueldelrio
June 1, 2026 7:28 am

Moderator – Do these “+” symbols hovering over my posts indicate some problem? Thanks!

migueldelrio
Reply to  migueldelrio
June 1, 2026 9:24 am
jonesingforozone
Reply to  migueldelrio
June 2, 2026 1:25 am

Jane Lubchenco, as a one-time NOAA Administrator, fueled the ocean acidification scare in her testimony before the House Select Committee on Energy Independence and Global Warming Dec. 2, 2009. Her testimony implied that gaseous CO2 converts directly into Carbonic acid when dissolved in water, using seashells and vinegar as props before the committee. I wonder if she actually believed it?

Reply to  jonesingforozone
June 2, 2026 9:55 pm

I see nothing in her background at Wikipedia that suggests that she had a strong background in chemistry.

jonesingforozone
Reply to  Clyde Spencer
June 3, 2026 8:53 am

She is a doctor of marine ecology. Even so, another marine biologist on this site was equally surprised by the ratio of dissolved CO2 versus [H2CO3] when reported 11 years ago. I bought Chemistry of the Climate System and found nothing concerning the ratio which varies a by such a small amount by temperature and salinity that the ratio is still 999 to 1.

jonesingforozone
Reply to  jonesingforozone
June 10, 2026 1:27 am

“Economist,” not “ecologist.”

jonesingforozone
Reply to  Clyde Spencer
June 3, 2026 12:25 pm

The motivation for using an intermediate solution to solve the fourth root is that one need only solve for three variables if the fourth root can be shown to be a constant.

The four variables are the individual carbon species:

a = [H2CO3]
b = [HCO3−]
c = [CO32−]
d = CO2(aq)

Taking the fourth root involves trigonometric calculations related to the instances of imaginary numbers. The texts, quite properly, combine terms, such that a’ = a + d:

a = [H2CO3] + CO2(aq)
b = [HCO3−]
c = [CO32−]

However, the texts forget the details of the simplification, returning the result a = [H2CO3] + CO2(aq), not a = [H2CO3], a much smaller number by 1/1000th.

The authors tend not to want to cause controversy, I suspect:

“Unfortunately, as noted by Dickson (1984), the field of pH scales and the study of acid-base reactions in seawater is one of the more confused areas of marine chemistry. The primary intent of measuring pH is to use it together with appropriated acid-dissociation constants (and other information – see section 1.2.5 above) to calculate the speciation of the various acid-base systems in seawater.” – from section 1.3.1 of “Part 1: Seawater carbonate chemistry” at [link deleted] http://www.epoca-project.eu/index.php/restricted-area/documents/doc_download/268-oa-guide-ch1-2010.html by Andrew G. Dickson.

jonesingforozone
Reply to  Clyde Spencer
June 3, 2026 1:15 pm

Score another one for the IAEA! The link has moved to PDF page 29 (doc page 27) of https://www.iaea.org/sites/default/files/18/06/oa-guide-to-best-practices.pdf

This discussion by Dickson resulted in early innovations in the marine biology field, not specifically to any fourth-root solution constants.

As a consequence, my claim still holds: Ignorance of basic chemistry [or a “not the boss of me” collegial attitude].

jonesingforozone
Reply to  Clyde Spencer
June 3, 2026 3:38 pm

Is this what is going on? Researchers ghost writing their bosses papers? Researchers who probably aren’t even aware of the “nuance” of mathematical substitution?? Incomprehensible???

Google AI, at https://www.google.com/search?q=when+the+dean%27s+away+the+researchers+will+play.&oq=when+the+dean%27s+away+the+researchers+will+play., says:

“Ah, the classic academic twist on the old playground proverb! Whenever the academic leadership is out of the office, out at a conference, or on sabbatical, the faculty and postdocs frequently take the opportunity to experiment, brainstorm, or enjoy a more relaxed lab environment.

Why the Research Keeps Going

When the dean—or the principal investigator (PI)—is away, the day-to-day pressure of administrative meetings and grant paperwork usually fades away. This shifting dynamic creates a few distinct opportunities:

Uninterrupted Flow: Without the constant stream of administrative drop-ins, researchers often experience a deeper “flow state,” knocking out complex data analysis or writing manuscripts.Brainstorming & Collaboration: Spontaneous, cross-departmental collaborations often spark during casual coffee breaks, leading to fresh grant proposals or papers.Lab Culture: It’s a great time for teams to bond over shared goals, celebrate recent milestones, or streamline their workflows without micromanagement.The Balancing Act

While the freedom is great for creativity and productivity, it also requires the research team to maintain momentum and handle potential lab equipment or supply issues independently.

Are you currently taking the lead on a project or running a lab while your supervisor is traveling? Let me know:

Are you working on data analysis, writing a draft, or troubleshooting an experiment?Do you need help organizing your workflow or generating a project timeline?Let me know what you’d like to tackle next!

AI responses may include mistakes.

I post this only partly in jest.

jonesingforozone
Reply to  Clyde Spencer
June 3, 2026 8:26 pm

TWTW reader Clyde Spencer writes: ‘I question whether a highly-buffered alkaline solution (sea water) can dissolve enough CO2 to truly become acidic. From reading in my college oceanography text, it appears that even in hydrogen sulfide-rich waters in ‘dead’ zones, sea water rarely even gets as low as pH 7 [neutral]. Club Soda, which is un-buffered and saturated with CO2, has a pH of about 5. That is probably the lowest fresh water can get with only carbonic acid present.’

I’m sure I was on the other side of that dialogue!

jonesingforozone
Reply to  Clyde Spencer
June 3, 2026 9:21 pm

Oh, no! I deleted my side of the posts! I found http://www.judithcurry.com, so I disavowed sunspot theory in favor of something more reasonable. I didn’t want people to believe that I had been abducted by a cult of GHGs! Quickly thought better of it but it was too late to save some posts.

jonesingforozone
Reply to  Clyde Spencer
June 3, 2026 9:49 pm

I played devils advocate on various and sundry minutia, but never once did Dr. Lief Svalgaard loose his temper. He was a true gentleman. He’d just say that, in the main, he was correct and that I was in [mod] because I had been a bad boy.

jonesingforozone
Reply to  Clyde Spencer
June 4, 2026 5:28 am

Of course, if there is no free CO2(aq), then there are no free H+ ions released as a consequence of dissolving CO2 into water. The ocean would become a permanent Carbon sink and all plant life would die.

jonesingforozone
Reply to  jonesingforozone
June 4, 2026 6:19 am

Put another way, if there are no CO2 molecules dissolved as CO2(aq), then there will be zero CO2 molecules to effervesce. See https://en.wikipedia.org/wiki/Carbonic_acid: “…Hence the majority of carbon dioxide at geophysical or biological air-water interfaces does not convert to carbonic acid, remaining dissolved CO2 gas,” or the 999/1000ths ratio posted previously.

jonesingforozone
Reply to  jonesingforozone
June 7, 2026 6:55 am

The more precise measurement of the hydration equilibrium constant for Carbonic acid, Kh, at 25°C is 1.2 × 10^-3 in seawater. – Soli, A. L.; R. H. Byrne (2002). CO2 system hydration and dehydration kinetics and the equilibrium CO2/H2CO3 ratio in aqueous NaCl solutionMarine Chemistry78 (2–3): 65–73. Bibcode:2002MarCh..78…65Sdoi:10.1016/S0304-4203(02)00010-5.

jonesingforozone
Reply to  jonesingforozone
June 10, 2026 1:28 am

…Therefore, ocean acidification has the unmistakable anthropogenic fingerprint of climate grift.

May 31, 2026 5:16 am

Ocean water is a well buffered solution. This means that any changes in pH by the addition of CO2 are limited by other chemical reactions.

jonesingforozone
Reply to  isthatright
June 3, 2026 7:00 am

Yes, it’s the salts that turn a weak acid, Carbonic acid, into a very weak acid.