Climate Geoengineering Prizewinner: Refreeze the Arctic with a Big Mobile Submarine

I believe you’ve missed the point, Bryan A. Ice melting while it is in water will not raise the water level. So the video purporting to stop sea level rise by creating sea-ice simply won’t work.

On top of that, the work required to desalinate the water and remove latent heat would dump even more heat into the environment, causing any existing ice to melt even faster. They’d literally be heating the Arctic, while claiming that they’re cooling it… but this wouldn’t be the first time science-denying climate alarmists came up with a solution which did the exact opposite of what they wanted it to do.

In fact, even the underlying premise of CAGW is a result of an inversion of reality based upon a flawed understanding of physics. Particle physics shows that CO2, above ~288 K, is a net atmospheric coolant.
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All radiative emission to space is, by definition, a cooling process. The only way our planet can shed energy is via radiative emission to space.

N2 and O2, comprising ~99% of the atmosphere, are homonuclear diatomics and therefore have no net magnetic dipole, rendering them unable to effectively emit (or absorb) IR. Thus the only way they can cool is via conduction by contact with a cooler surface, or via transfer of their translational mode energy to the vibrational mode quantum state energy of radiative molecules.
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The radiative cooling of air via solely translational mode energy converting to radiation
CO2{v20(0)} (at 288K+) + CO2{v20(0)} (at 288K+) -> CO2{v20(0)} + C02{v21(1)} -> CO2{v20(0)} + CO2{v20(0)} + 667.4 cm-1

You’ll note the above interaction is a direct conversion of translational mode energy (which we perceive as temperature) to 14.98352 µm radiation. This directly cools the air, and the effect is significant, since nearly all the translational mode energy is converted to radiation, leaving the CO2 molecules at a very low temperature, whereupon they absorb energy by colliding with other atmospheric constituents. The effect begins taking place significantly at ~288 K, the temperature at which the majority of the molecules will have sufficient translational mode energy to convert to vibrational mode energy.

288 K also happens to be the stated average global temperature… that is not a coincidence, it is a mechanism long known, partly a result of CO2 radiative emission ramping up at ~288 K. As CO2 concentration increases, this effect will become more pronounced, increasingly damping any temperature excursions above ~288 K by increase of radiative emission via this interaction, and below ~288 K by reduction of radiative emission via this interaction.

It is not necessary for CO2{v20(0)} to collide with another CO2 molecule for this interaction to take place, any other molecule will do… the Equipartition Theorem dictates that all atmospheric constituents at the same temperature will have the same translational mode energy. So in reality, the above interaction could be represented thusly:
X (at 288K+) + CO2{v20(0)} (at 288K+) -> X + C02{v21(1)} -> X + CO2{v20(0)} + 667.4 cm-1
where X is any atmospheric molecule.

Further, you’ll note that if a CO2 molecule is already in the CO2{v21(1)} vibrational mode quantum state, a collision at just 0.1 K higher temperature (ie: ~288.1 K) can excite it to the CO2{v22(2)} state, whereupon it can emit a 14.97454 µm photon to de-excite to the CO2{v21(1)} state, and a 14.98352 µm photon to de-excite to the CO2{v20(0)} state.

Even further, you’ll note that if a CO2 molecule is already in the CO2{v22(2)} vibrational mode quantum state, a collision at just 0.1 K higher temperature (ie: ~288.2 K) can excite it to the CO2{v23(3)} state, whereupon it can emit a 14.96782 µm photon to de-excite to the CO2{v22(2)} state, a 14.97454 µm photon to de-excite to the CO2{v21(1)} state, and a 14.98352 µm photon to de-excite to the CO2{v20(0)} state.

This implies that for temperatures above ~288 K, more of the translational energy of atmospheric molecules will flow to CO2 vibrational mode quantum state energy, rather than vibrational mode quantum state energy of CO2 flowing to translational energy of other atmospheric molecules, simply for the fact that at and above that temperature, the combined translational energy of two colliding molecules is sufficient to excite the CO2 vibrational modes. This increases the time duration of CO2 vibrational mode quantum state excitation and therefore the probability that CO2 will radiatively emit, breaking LTE. Therefore the energy flow is to CO2, not from it.

In other words, at and above ~288 K, the combined translational mode energy of two molecules is higher than C02{v21(1)} vibrational mode energy, and therefore energy will flow to CO2 from other atmospheric molecules’ translational mode energy during molecular collision, simply because CO2 can radiatively emit that energy and break LTE, rather than that energy flowing back to other molecules.

You’ll note that’s diametrically opposite to the claimed mechanism by which CO2 purportedly causes global warming. Liberals tend to invert reality, and rely upon the low standard of education to sustain that inversion’s claims.
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Satellites see CO2 and (a bit of) water vapor radiating at the temperature of the lower stratosphere (at the ‘characteristic-emission surface’ altitude, or just less than one optical depth from TOA for any given wavelength) all over the planet. This is because ozone (O3, excited by incoming solar radiation) and collisional processes excite nitrogen (N2) to its {v1(1)} (symmetric stretch) vibrational mode, and N2 then transfers energy to the {v3(1)} (asymmetric stretch) mode of CO2 via collision as shown in the image, whereupon the vibrationally excited CO2 partially de-excites by dropping from the {v3(1)} (asymmetric stretch) mode to either the {v1(1)} (symmetric stretch) mode by emitting a 10.4 µm photon, or to the {v20(2)} (bending) mode by emitting a 9.4 µm photon.

This is the same method by which a CO2 laser works… the laser filling gas within the discharge tube consists of around 10–20% carbon dioxide (CO2), around 10–20% nitrogen (N2), and a few percent hydrogen (H2) and/or xenon (Xe), and the remainder helium (He). Electron impact vibrationally excites the N2 to its first vibrational mode quantum state {v1(1)}, the N2 collides with CO2, the CO2 becomes excited in the asymmetric stretch vibrational mode quantum state {v3(1)}, and de-excites to its {v1(1)} or {v20(2)} vibrational modes by emission of 9.4 µm or 10.4 µm radiation (wavelength dependent upon isotopic composition of the CO2 molecules) as described above. The helium is used to fully de-excite the CO2 to the {v20(0)} ground state after it’s radiatively de-excited to maintain population inversion (which is necessary for stimulated emission), but this is unimportant to the process of energy transfer from vibrationally excited N2 to CO2 in the atmosphere. The process by which the N2 becomes vibrationally excited (in the case of a CO2 laser via electron impact; in the atmosphere via translational-to-vibrational collisional processes and via vibrational-to-vibrational collisional processes with solar-excited O3) is similarly unimportant… the concept of energy flowing from N2 to CO2 is the same. Laser wavelength can be tuned by altering the isotopic ratio of the carbon and oxygen atoms comprising the CO2 molecules in the discharge tube, with heavier isotopes resulting in longer wavelength emission.

The Boltzmann Factor shows that ~10.26671% of N2 molecules are in the N2{v1(1)} excited state at 288 K due to collisional (t-v) processes. That’s 195 times more excited N2 molecules than all CO2 molecules (vibrationally excited or not).
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