I’m a bit skeptical of this claim, “Satellite images reveal ocean acidification from space” but it may be mostly due to how the press release is written, for example, nowhere is the term pH used in the press release, though it is in the abstract. Curiously, the caption for the graphic provided with the press release says it is “total ocean alkalinity from space” which is actually correct, since the ocean pH is not below 7.0, and not acidic, it is simply less alkaline. Then there’s the statement “The new techniques use satellite mounted thermal cameras to measure ocean temperature while microwave sensors measure the salinity.” This makes the measurement appear more like a proxy for OA than direct measurement. Dr. Roy Spencer comments on this and the technology below.

From the University of Exeter:
Pioneering techniques that use satellites to monitor ocean acidification are set to revolutionize the way that marine biologists and climate scientists study the ocean.
This new approach, which will be published on the 17 February 2015 in the journal Environmental Science and Technology, offers remote monitoring of large swathes of inaccessible ocean from satellites that orbit the Earth some 700 km above our heads.
Each year more than a quarter of global CO2 emissions from burning fossil fuels and cement production are taken up by the Earth’s oceans. This process turns the seawater more acidic, making it more difficult for some marine life to live. Rising CO2 emissions, and the increasing acidity of seawater over the next century, has the potential to devastate some marine ecosystems, a food resource on which we rely, and so careful monitoring of changes in ocean acidity is crucial.
Researchers at the University of Exeter, Plymouth Marine Laboratory, Institut français de recherche pour l’exploitation de la mer (Ifremer), the European Space Agency and a team of international collaborators are developing new methods that allow them to monitor the acidity of the oceans from space.
Dr Jamie Shutler from the University of Exeter who is leading the research said: “Satellites are likely to become increasingly important for the monitoring of ocean acidification, especially in remote and often dangerous waters like the Arctic. It can be both difficult and expensive to take year-round direct measurements in such inaccessible locations. We are pioneering these techniques so that we can monitor large areas of the Earth’s oceans allowing us to quickly and easily identify those areas most at risk from the increasing acidification.”
Current methods of measuring temperature and salinity to determine acidity are restricted to in situ instruments and measurements taken from research vessels. This approach limits the sampling to small areas of the ocean, as research vessels are very expensive to run and operate.
The new techniques use satellite mounted thermal cameras to measure ocean temperature while microwave sensors measure the salinity. Together these measurements can be used to assess ocean acidification more quickly and over much larger areas than has been possible before.
Dr Peter Land from Plymouth Marine Laboratory who is lead author of the paper said: “In recent years, great advances have been made in the global provision of satellite and in situ data. It is now time to evaluate how to make the most of these new data sources to help us monitor ocean acidification, and to establish where satellite data can make the best contribution.”
A number of existing satellites can be used for the task; these include the European Space Agency’s Soil Moisture and Ocean Salinity (SMOS) sensor that was launched in 2009 and NASA’s Aquarius satellite that was launched in 2011.
The development of the technology and the importance of monitoring ocean acidification are likely to support the development of further satellite sensors in the coming years.
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The research is published in the scientific journal Environmental Science and Technology.
Source: Eurekalert http://www.eurekalert.org/pub_releases/2015-02/uoe-sir021315.php
Salinity from Space Unlocks Satellite-Based Assessment of Ocean Acidification
Land et al.
Synopsis
Approximately a quarter of the carbon dioxide (CO2) that we emit into the atmosphere is absorbed by the ocean. This oceanic uptake of CO2 leads to a change in marine carbonate chemistry resulting in a decrease of seawater pH and carbonate ion concentration, a process commonly called “Ocean Acidification”. Salinity data are key for assessing the marine carbonate system, and new space-based salinity measurements will enable the development of novel space-based ocean acidification assessment. Recent studies have highlighted the need to develop new in situ technology for monitoring ocean acidification, but the potential capabilities of space-based measurements remain largely untapped. Routine measurements from space can provide quasi-synoptic, reproducible data for investigating processes on global scales; they may also be the most efficient way to monitor the ocean surface. As the carbon cycle is dominantly controlled by the balance between the biological and solubility carbon pumps, innovative methods to exploit existing satellite sea surface temperature and ocean color, and new satellite sea surface salinity measurements, are needed and will enable frequent assessment of ocean acidification parameters over large spatial scales.
Dr. Roy Spencer, a remote sensing specialist himself, comments to me via email:
The technique for measuring salinity with low-frequency microwave
measurements is nothing new, although we haven’t had satellites to do it
globally until relatively recently. But I’m not aware of how you get pH
from salinity and temperature…never heard of that before.
I did find this paper on satellite instrumentation designed to measure salinity:
http://ntrs.nasa.gov/archive/nasa/casi.ntrs.nasa.gov/20050139772.pdf
So if they are using temperature and salinity to come up with pH, how can they determine that the “ocean acidification” they claim in the PR is truly a function of dissolved CO2, and not just part of the normal regional and seasonal salinity pattern? That concern is backed up by one of the images in a photo collage they present with the paper, which shows what seems to be a salinity image from the Aquarius instrument, note the arrow:
I found NASA’s press release on the first full year of salinity measurements using the Aquarius instrument and an interesting image similar to what is presented in the Land et al. press release.
Putting that image next to the one they provide with the press release suggests they are simply measuring a a dominant effect of seasonal and regional salinity variation, and not CO2 driven “ocean acidification”:

Note how similar the ocean regional patterns are. NASA writes of the salinity image:
One of the features that stand out most clearly is a large patch of highly saline water across the North Atlantic. This area, the saltiest anywhere in the open ocean, is analogous to deserts on land, where little rainfall and a lot of evaporation occur. A NASA-funded expedition, the Salinity Processes in the Upper Ocean Regional Study (SPURS), traveled to the North Atlantic’s saltiest spot to analyze the causes behind this high salt concentration and to validate Aquarius measurements.
So it seems Land et al. (2015) isn’t actually measuring CO2 driven OA.
And more importantly, how did Land et al. (2015) calibrate the proxy for pH? Have they sent ships to do in situ sampling as NASA did? There seems to be no mention of it…except that calibration of their algorithms is sorely needed. From page 3 of the paper:
Wow. Their own paper emphasizes the need for in situ measurement, and that the algorithms aren’t calibrated.
It seems to me that they are still a long way from the claims made in the press release that they can reliably measure ocean pH via satellite remote sensing over time. I wonder if Dr. Land is happy with how the press release makes claims about the work?
Sadly, this press release seems to fit the hype pattern discussed yesterday: From #AAAS Why Some (Many?) Scientists Tend to Hype their Findings
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Not sure whether anyone already pointed this out but the graphic associated with this paper seems to show an inverse relationship to the high-CO2 regions recently mapped by NASA.
The red areas on the graph correspond with areas where the oceans are releasing CO2 and the blue areas correspond with areas where the ocenas are absorbing CO2.
This confirms the data from NASA’s CO2 observer. CO2 is being released by the oceans with negligible contribution from industrialized nations.
http://www.nasa.gov/sites/default/files/styles/673xvariable_height/public/thumbnails/image/mainco2mappia18934.jpg?itok=Cr0RkkGC
Reblogged this on gottadobetterthanthis and commented:
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Hype without data, without explanation, is sad.
You must not fool yourself, and you are the easiest to fool. It seems the folks involved with such papers are either fools fooling themselves, or they are shysters hoping to fool us.
It’s worse than we thought, the state of climate science that is. I have no idea how microwaves determine salinity and to what depth they do this, or if it is a measurement of the surface, but infrared based satellite temperatures are only measuring the surface and do not show temperature at depth. I assume they infer a conductivity from the salinity and then infer a pH of the surface from the temperature and conductivity. So what is surface pH going to tell us? Jack sh!t. The data is going to be contaminated by rain and evaporation and it isn’t an accurate representaion for the pH just under the surface. It’s like trying to describe atmospheric conditions at the earth’s surface by collecting data on the tropopause.
But it doesn’t matter anyways, because chemistry. The oceans are not a closed system, they do not have a fixed amount of carbonates like in a beaker back at the lab. If CO3 ions are depleted by increased CO2 ions then solid CaCO3 from the unlimited CaCO3 sediment supply simply goes into solution. Much of the CO2 will simply remain as dissolved CO2 anyways and increase photosynthetic efficiency.
“This process turns the seawater more acidic, making it more difficult for some marine life to live”
Bogus claim as seawater is a complex buffer system and very resistant to a weak acid such as carbonic acid from CO2. But, dissolved CO2 will push the carbonic acid, bicarbonate, carbonate, calcium carbonate to the product side, causing deposition of calcium carbonate.
The map shown is not pH change, it’s just pH measurement. They cannot show and pH decrease. Ocean pH remains within its normal range.
I don’t understand your first paragraph. In lime/soda softening water treatment we introduce CO2 to change calcium carbonate that hasn’t settled out yet or is still dissolved back into bicarbonates so they won’t settle out or scale in the distribution system.
Did I misunderstand what you meant?
There’s a big difference between the chemistry of freshwater and seawater.
Ben of Houston http://wattsupwiththat.com/2015/02/17/claim-versus-pr-hype-doesnt-hold-up-satellite-images-reveal-ocean-acidification-from-space/#comment-1861866
Damn skippy!! If I submitted cooling tower blowdown with surrugate and correlative data, I’d be in prison along with my plant manager and maybe supervisor. Hell, for that matter if I dump a cooling pond and conduct all the biomonitoring, temperature, pH, oil and grease, TSS, flow, etc. data and it all passes. The fleas, ticks, and fish (as my plant manager calls them) propagate spectacularly and fart rainbows.
But…. If I fill the pond back up from the receiving stream two weeks later and decide I forgot to fix a spray support standard and dump it right back and have neither circulated the water or put anything in it, and don’t conduct all that testing all over again…… yep, NOV/fine/bad publicity in the press/etc. so forth ad nauseum
I have to love this type of “scientific research.” Use an instrument designed for one specific thing and another designed for something else and try to cobble a process that gives peripheral information that supports a totally different process. Sort of like going to the paint store and getting the color swatches to determine how dirty the wash water really is.
Maybe if we filled the Oceans with Universal Indicator Solution
http://en.wikipedia.org/wiki/Universal_indicator
Then the Satellites could see what colour it turned
Have they any idea about the innate carbonate buffering is built into the oceans.If this wasn’t the case – and in our own cellular processes with a carried ocean – we wouldn’t be here.
Doh! – just realised…. it would be Blue
At least there’d be no more red tides. 😎
Here are the chemical reactions and content of seawater that determine average pH = 8.1
H2O + CO2 H2CO3 H+ + HCO3-
CO2 = 1 mole, HCO3- = 1.2 mole, H+ = 1/256,000 mole
Obviously there is an oversupply of bicarbonates relative to hydrogen ions. by Le Chatelier’s principle, equilibrium shifts to the left side of the reaction favoring the formation of carbonic acid over formation of hydrogen ions.
The world’s proven oil reserves equal 1.48 x 10^12 barrels. If we burn all that, it will produce 6.36 x 10^14 kg of CO2. One-fourth of that is believed to be absorbed by the ocean. It will only increase dissolved CO2 in the ocean by 1% or in the above equation from 1 to 1.01 mole of CO2. The effect is negligible. It will not shift the chemical equilibrium. pH will change from 8.10 to 8.08
The double arrows disappeared. Here it is again.
H2O + CO2 = H2CO3 = H+ + HCO3-
Equal sign represents double arrow or reversible reaction
Dr Strangelove
Yeah, well there you are again.
Bringing numbers to a knife fight.
Ocean acidification? Really? Where? Only in mythical research!
The popular version used by Scientific American and 350.org originates with Brian Kahn, Senior Science Writer at Climate Central, (MA in “Climate and Society” from Columbia) experienced in producing “multimedia stories and managing social media campaigns”.
“The depressing task of monitoring ocean acidification..” and “….global warming’s evil twin at work”
are of course sober scientific speak which only Scientists can understand. No fingerprint of spinmeisters can be detected.
http://www.scientificamerican.com/article/watch-ocean-acidification-in-real-time/?utm_content=bufferab80c&utm_medium=social&utm_source=twitter.com&utm_campaign=buffer
“We expect that many of these algorithms will perform poorly on a global scale,” Gory details here:
http://www.pathfinders-oceanacidification.org/var/storage/images/medias-ifremer/medias-oceanacidification/images/carbonate_system/1006540-1-eng-GB/carbonate_system_catcher.png
http://www.pathfinders-oceanacidification.org/var/storage/images/medias-ifremer/medias-oceanacidification/images/carbonate_system/1006540-1-eng-GB/carbonate_system.png