I find this paper (PDF) interesting, but it still does not address the temperature/CO2 800 year time lag seen in ice core records. h/t to Leif Svalgaard – Anthony
Fossil soils constrain ancient climate sensitivity
Dana L. Royer 1
Department of Earth and Environmental Sciences, Wesleyan University, Middletown, CT 06459
Global temperatures have covaried with atmospheric carbon dioxide (CO2) over the last 450 million years of Earth’s history (1). Critically, ancient greenhouse periods provide some of the most pertinent information for anticipating how the Earth will respond to the current anthropogenic loading of greenhouse gases. Paleo-CO2 can be inferred either by proxy or by the modeling of the long-term carbon cycle.

For much of the geologic past, estimates of CO2 are consistent across methods (1). One exception is the paleosol carbonate proxy, whose CO2 estimates are often more than twice as high as coeval estimates from other methods (1). This discrepancy has led some to question the validity of the other methods and has hindered attempts to understand the linkages between paleo-CO2 and other parts of the Earth system. In this issue of PNAS, Breecker and colleagues (2) break important new ground for resolving this conflict.
The paleosol carbonate proxy for atmospheric CO2 is based on the analysis of carbonate nodules that precipitate in soils in seasonally dry to dry climates. These nodules incorporate carbon from two sources: atmospheric CO2 that diffuses directly into the soil and in situ CO2 from biological respiration. Because the stable carbon isotopic composition of these two sources is distinct, the concentration of atmospheric CO2 can be inferred if the concentration of soil CO2 and the isotopic compositions of the two sources are known (3). Atmospheric CO2 estimates scale directly with soil CO2 concentration: If the soil term is wrong by a factor of two, the inferred atmospheric CO2 will be off by a factor of two.
Estimates of soil CO2 concentration for fossil soils have been based on measurements taken during the growing season in equivalent living soils. However, Breecker et al. (2, 4) demonstrate convincingly that the window of active carbonate formation is restricted to the warmer and dryer parts of the growing season. Carbonate formation is simply not thermodynamically favorable during cooler and wetter seasons. Critically, biological productivity and respiration are low during these dry periods. As a result, soil CO2 concentration during the critical window of active carbonate formation has been overestimated in most soils by a factor of two or more (2).
What does this mean? CO2 estimates from the paleosol carbonate proxy can be cut in half (or more). Doing so snaps the paleosol-based estimates in line with most other approaches (2) (Fig. 1B) and produces the most precise view to date of Earth’s CO2 history. We are now better equipped to answer some important, basic questions. For example, what is the quantitative relationship between CO2 and temperature? That is, for every doubling of CO2, what is the long-term (103–104 years) equilibrium response of global temperature (termed here climate sensitivity)?
Most assessments of climate sensitivity for the present day hover around 3°C per CO2 doubling (5), although if the longterm waxing and waning of continental ice sheets are considered it is probably closer to 6°C (6). Less is known about climate sensitivity during ancient greenhouse periods, simply because having poles draped in forest instead of ice represents a profound rearrangement of climate feedbacks.
Records of CO2 and temperature are now sufficiently robust for placing firm minimum constraints on climate sensitivity during parts of the Cretaceous and early Paleogene (125–40 Mya), a well-known globally warm interval. Indeed, owing to the logarithmic relationship between CO2 and temperature, the geologic record is ideally suited for establishing minimum thresholds. This is because, to accommodate a declining sensitivity, other boundary conditions of the Earth system need to shift exponentially, for example, unreasonable oscillations in atmospheric CO2. Policywise, establishing a basement value for climate sensitivity is a critical step for addressing our current climate crisis (5).
With few exceptions, CO2 during the Cretaceous and early Paleogene was<1,000 ppm (2) (Fig. 1B). Global mean surface temperature is very difficult to establish for these ancient periods. However, temperature change in the tropics today scales at roughly two-thirds the global change (5, 6).
If we assume a similar relationship in the past and a climate sensitivity of 3°C perCO2 doubling, a rise in atmospheric CO2 to 1,000 ppm results in a 3.6°C warming in the tropics (relative to a 280-ppm baseline).
Given that tropical sea surface temperatures range from 27° to 29°C today, tropical temperatures exceeding 30.6°–32.6°C (red band in Fig. 1A) during the Cretaceous and early Paleogene likely correspond to a climate sensitivity >3°C. This threshold was commonly surpassed during the Cretaceous and early Paleogene (Fig. 1A). For times when CO2 was <1,000 ppm, the tropical temperature threshold for a 3°C climate sensitivity would shift to correspondingly cooler values.
Further, there is abundant evidence for flatter latitudinal temperature gradients during greenhouse periods (7, 8), meaning, again, that the tropical temperature threshold used here is probably a maximum. Together, it is clear that during the Cretaceous and Paleogene climate sensitivity commonly exceeded 3°C per CO2 doubling.
Although further work is needed, the geologic evidence (2) (Fig. 1) is most consistent with long-term, future climate change being more severe than presently anticipated (5). Also, global climate models tuned to ancient greenhouse periods commonly have emergent climate sensitivities of <3°C and they fail to simulate the shallow latitudinal temperature gradients (9). Thus even for times with little ice, there are important positive feedbacks that are presently not captured adequately in climate models. Processes for warming the high latitudes without a change in CO2 include more vigorous heat transport (10, 11), more widespread stratospheric clouds in the high latitudes (12), and climate feedbacks from polar forests (13). and their study highlights the value of a clearly resolved paleo-CO2 record. However, a limitation is that they uniformly apply a “best guess” value of 2,500 ppm for soil CO2 concentration.
They recognize this as an oversimplification and is an area for future work. Better modeling of the term, perhaps through independent proxy (14), may result in a further tightening of the paleo-CO2 record.
1. Royer DL (2006) CO2-forced climate thresholds during the Phanerozoic. Geochim Cosmochim Acta 70:5665– 5675.
2. Breecker DO, Sharp ZD, McFadden LD (2010) Atmospheric CO2 concentrations during ancient greenhouse climates were similar to those predicted for 2100 A.D. Proc Natl Acad Sci USA 107:576–580.
3. Cerling TE (1991) Carbon dioxide in the atmosphere: Evidence from Cenozoic and Mesozoic paleosols. Am J Sci 291:377–400.
4. Breecker DO, Sharp ZD, McFadden LD (2009) Seasonal bias in the formation and stable isotopic composition of pedogenic carbonate in modern soils from central New Mexico, USA. Geol Soc Am Bull 121:630–640.
5. IPCC (2007) Climate Change 2007: The Physical Science Basis, Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change (Cambridge Univ Press, Cambridge, UK).
6. Hansen J, et al. (2008) Target atmospheric CO2: Where should humanity aim? Open Atmospheric Sci J 2: 217–231.
7. Bice KL, Huber BT, Norris RD (2003) Extreme polar warmth during the Cretaceous greenhouse? Paradox of the late Turonian δ18O record at Deep Sea Drilling Project Site 511. Paleoceanography 18:1031.
8. Bijl PK, et al. (2009) Early Palaeogene temperature evolution of the southwest Pacific Ocean. Nature 461: 776–779.
9. Shellito CJ, Sloan LC, Huber M (2003) Climate model sensitivity to atmospheric CO2 levels in the Early-Middle Paleogene. Palaeogeogr Palaeoclimatol Palaeoecol 193: 113–123.
10. Korty RL, Emanuel KA, Scott JR (2008) Tropical cycloneinduced upper-ocean mixing and climate: Application to equable climates. J Clim 21:638–654.
11. Ufnar DF, González LA, Ludvigson GA, Brenner RL, Witzke BJ (2004) Evidence for increased latent heat transport during the Cretaceous (Albian) greenhouse warming. Geology 32:1049–1052.
12. Abbot DS, Tziperman E (2008) Sea ice, high-latitude convection, and equable climates. Geophys Res Lett 35:L03702.
13. Beerling DJ, Nicholas Hewitt C, Pyle JA, Raven JA (2007) Critical issues in trace gas biogeochemistry and global change. Philos Trans R Soc Lond A 365:1629–1642.
14. Retallack GJ (2009) Refining a pedogenic-carbonate CO2 paleobarometer to quantify a middle Miocene greenhouse spike. Palaeogeogr Palaeoclimatol Palaeoecol 281:57–65.
15. Bice KL, et al. (2006) A multiple proxy and model study of Cretaceous upper ocean temperatures and atmospheric CO2 concentration. Paleoceanography 21: PA2002.
16. Bornemann A, et al. (2008) Isotopic evidence for glaciation during the Cretaceous supergreenhouse. Science 319:189–192.
17. Forster A, Schouten S, Baas M, Sinninghe Damsté JS (2007) Mid-Cretaceous (Albian Santonian) sea surface temperature record of the tropical Atlantic Ocean. Geology 35:919–922.
18. Forster A, Schouten S, Moriya K, Wilson PA, Sinninghe Damsté JS (2007) Tropical warming and intermittent cooling during the Cenomanian/Turonian oceanic anoxic event 2: Sea surface temperature records from the equatorial Atlantic. Paleoceanography 22:PA1219.
19. Moriya K, Wilson PA, Friedrich O, Erbacher J, Kawahata H (2007) Testing for ice sheets during the mid-Cretaceous greenhouse using glassy foraminiferal calcite from the mid-Cenomanian tropics on Demerara Rise. Geology 35:615–618.
20. Norris RD, Bice KL, Magno EA, Wilson PA (2002) Jiggling the tropical thermostat in the Cretaceous hothouse. Geology 30:299–302.
21. Pearson PN, et al. (2001) Warm tropical sea surface temperatures in the Late Cretaceous and Eocene epochs. Nature 413:481–487.
22. Pearson PN, et al. (2007) Stable warm tropical climate through the Eocene Epoch. Geology 35:211–214.
23. Schouten S, et al. (2003) Extremely high sea-surface temperatures at low latitudes during the middle Cretaceous as revealed by archaeal membrane lipids. Geology 31:1069–1072.
24. Tripati A, et al. (2003) Tropical sea-surface temperature reconstruction for the early Paleogene using Mg/Ca ratios of planktonic foraminifera. Paleoceanography 18:1101.
25. Wagner T, et al. (2008) Rapid warming and salinity changes of Cretaceous surface waters in the subtropical North Atlantic. Geology 36:203–206.
26. Wilson PA, Norris RD (2001) Warm tropical ocean surface and global anoxia during the mid-Cretaceous period. Nature 412:425–429.
27. Wilson PA, Norris RD, Cooper MJ (2002) Testing the Cretaceous greenhouse hypothesis using glassy foraminiferal calcite from the core of the Turonian tropics on Demerara Rise. Geology 30:607–610.
28. Wilson PA, Opdyke BN (1996) Equatorial sea-surface temperatures for the Maastrichtian revealed through remarkable preservation of metastable carbonate. Geology 24:555–558.
29. Sexton PF, Wilson PA, Pearson PN (2006) Microstructural and geochemical perspectives on planktic foraminiferal preservation: “glassy” versus “frosty”. Geochem Geophys Geosyst 7:Q12P19.
30. Pagani M, Lemarchand D, Spivack A, Gaillardet J (2005) A critical evaluation of the boron isotope-pH proxy: The accuracy of ancient ocean pH estimates. Geochim Cosmochim Acta 69:953–961.
Discover more from Watts Up With That?
Subscribe to get the latest posts sent to your email.
The cyclicity that it fairly apparent in the temperature data would suggest that the major cause is climate oscillations (PDO, NAO, AMO, etc.). All of which are probably manifestations of the ENSO. The ENSO itself might be driven by solar fluctuations… It could even be related to upper mantle convection. I don’t even have a good guess as to what drives the ENSO.
I doubt that the upper 700m of the oceans are losing heat to the next deeper 1300m.
I haven’t read Von Schuckman, beyond the abstract, but I seem to recall reading that it was only based on the Argo data. Whereas, Levitus used both Argo and XBT data. Furthermore, I think the correction to Levitus which produced the negative flux since 2003 was published about a year after Von Schuckman.
NASA, NOAA and other groups have been constantly trying to figure out the best way to integrate the Argo and XBT data since 2005-2006 after NASA reported a sudden cooling of the oceans in 2003. A report they later retracted.
If the climate is in the process of a major transition, like the “Great Pacific Climate Shift” of 1976-1977, it would seem to not be too much of a logical jump to assume that ocean heat content should be acting “funny”.
I don’t think that the solar minima and maxima act that quickly on climate. They have to be translated through the atmosphere and oceans to drive the multitude of climate oscillations. And I doubt that Asian aerosols are causing the current warming hiatus or slight cooling any more than Euro-American aerosols caused the slight cooling from ~1942 to ~1976… Or that European black carbon caused the warming from ~1908 to ~1942.
It really stretches credulity to think that these anthropogenic effects are oscillating on such a regular schedule… A schedule that happens to coincide with the phases of the AMO, NAO, PDO, ENSO, etc.
As a far as “a of more vigorous warming”… It will happen. But it will happen about 20-30 years from now. If people should be worried about climate change, they should be worried about how much it might cool over the next 20-30 years. If the solar minima are really instructive about climate change and we are in a Dalton-style minimum, it’s going to be getting quite a bit colder. If we get 1 or 2 Pinatubo’s over the next couple of decades, it’ll be even colder.
We have a lot more people to feed now than we had back in 1815;
I wonder if anyone has ever analyzed the plant remains from the initiation of the last ice-age to see if there was any evidence of global CO2 starvation. I am sure that it would be fairly easy to get grant money for such a study.
@Spector (11:11:52) :
There is quite a lot of evidence of CO2 starvation during Pleistocene glacial episodes… Carbon starvation in glacial trees recovered from the La Brea tar pits, southern California
CO2 starvation becomes an issue for many plants at less than 200 ppmv, particularly C3 plants.