Study shows CFCs, cosmic rays major culprits for global warming

http://www.physast.uga.edu/~jss/1010/ch10/ozone_hole.jpg
Ozone at Antarctica - Image NASA

From the University of Waterloo press release.

WATERLOO, Ont. (Monday, Dec. 21, 2009) – Cosmic rays and chlorofluorocarbons (CFCs), both already implicated in depleting the Earth’s ozone layer, are also responsible for changes in the global climate, a University of Waterloo scientist reports in a new peer-reviewed paper.

In his paper, Qing-Bin Lu, a professor of physics and astronomy, shows how CFCs – compounds once widely used as refrigerants – and cosmic rays – energy particles originating in outer space – are mostly to blame for climate change, rather than carbon dioxide (CO2) emissions. His paper, derived from observations of satellite, ground-based and balloon measurements as well as an innovative use of an established mechanism, was published online in the prestigious journal Physics Reports.

“My findings do not agree with the climate models that conventionally thought that greenhouse gases, mainly CO2, are the major culprits for the global warming seen in the late 20th century,” Lu said. “Instead, the observed data show that CFCs conspiring with cosmic rays most likely caused both the Antarctic ozone hole and global warming. These findings are totally unexpected and striking, as I was focused on studying the mechanism for the formation of the ozone hole, rather than global warming.”

His conclusions are based on observations that from 1950 up to now, the climate in the Arctic and Antarctic atmospheres has been completely controlled by CFCs and cosmic rays, with no CO2 impact.

“Most remarkably, the total amount of CFCs, ozone-depleting molecules that are well-known greenhouse gases, has decreased around 2000,” Lu said. “Correspondingly, the global surface temperature has also dropped. In striking contrast, the CO2 level has kept rising since 1850 and now is at its largest growth rate.”

In his research, Lu discovers that while there was global warming from 1950 to 2000, there has been global cooling since 2002. The cooling trend will continue for the next 50 years, according to his new research observations.

As well, there is no solid evidence that the global warming from 1950 to 2000 was due to CO2. Instead, Lu notes, it was probably due to CFCs conspiring with cosmic rays. And from 1850 to 1950, the recorded CO2 level increased significantly because of the industrial revolution, while the global temperature kept nearly constant or only rose by about 0.1 C.

In previously published work, Lu demonstrated that an observed cyclic hole in the ozone layer provided proof of a new ozone depletion theory involving cosmic rays, which was developed by Lu and his former co-workers at Rutgers University and the Université de Sherbrooke. In the past, it was generally accepted for more than two decades that the Earth’s ozone layer is depleted due to the sun’s ultraviolet light-induced destruction of CFCs in the atmosphere.

The depletion theory says cosmic rays, rather than the sun’s UV light, play the dominant role in breaking down ozone-depleting molecules and then ozone. In his study, published in Physical Review Letters, Lu analyzed reliable cosmic ray and ozone data in the period of 1980-2007, which cover two full 11-year solar cycles.

In his latest paper, Lu further proves the cosmic-ray-driven ozone depletion theory by showing a large number of data from laboratory and satellite observations. One reviewer wrote: “These are very strong facts and it appears that they have largely been ignored in the past when modelling the Antarctic ozone loss.”

New observations of the effects of CFCs and cosmic rays on ozone loss and global warming/cooling could be important to the Earth and humans in the 21st century. “It certainly deserves close attention,” Lu wrote in his paper, entitled Cosmic-Ray-Driven Electron-Induced Reactions of Halogenated Molecules Adsorbed on Ice Surfaces: Implications for Atmospheric Ozone Depletion and Global Climate Change.

The paper, published Dec. 3 in Physics Reports, is available online at: dx.doi.org/10.1016/j.physrep.2009.12.002.

h/t to Russ Steele


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johnh
December 22, 2009 10:24 am

But back in 2005 this was said ref Ozone hole
“Global warming might actually delay the healing of the ozone layer or altogether worsen the issue,” he said.
http://www.msnbc.msn.com/id/9369129/
Its have your cake and eat it, global warming causes the hole but the hole causes cooling.
Well that sort of tortured logic just about says it all

Ben
December 22, 2009 10:24 am

“…Correspondingly, the global surface temperature has also dropped. In striking contrast, the CO2 level has kept rising since 1850 and now is at its largest growth rate…” CO2 is now at its largest growth rate? Since when, I wonder? NOAA’s information for Mauna Loa shows what appears to be a linear relationship from 1960 to the present here:
http://www.esrl.noaa.gov/gmd/ccgg/trends/co2_data_mlo.html
which is less than indicative of the “largest growth rate.” If there is a difference, it is not readily discernible from the graph, a condition which I would expect from such a statement.
The question becomes: where did Professor Lu get his data, and where was it collected? For example, did the “growth rate” dramatically increase upon siting the measurement station near an urban center, dairy farm, other volcano that is currently erupting?

Harry
December 22, 2009 10:26 am

Nope. This isnt going to work. We cant extort money and power over CFC’s. We’re going to have to stick with CO2.

kadaka
December 22, 2009 10:27 am

George E. Smith (09:32:28) :
Well it is pretty remarkable that someone can come out of the blue and simply claim that “it ain’t CO2″.

It is amazingly remarkable that such a paper was allowed to be published. Now, it does state there was warming, and it was human caused although by a different model than CO2, so it may have slipped by the CRU crew unnoticed. But it does seem to indicate that, post Climategate, the “peer reviewed literature” is allowing at least alternate theories for the warming to be published.
Of course, I wonder what data that shows warming was used, that this theory accounts for. If it matches the “value added” data, it could end up being invalidated. Once the raw data is located, gathered, properly adjusted by non-biased methods, and tallied up, this theory may account for far more warming than there actually was. Heck, maybe we’ll find out the trees weren’t lying with their “divergence problem” and there could actually have been some cooling in that period.
Still, it is a non-CO2 model, and if it matches the temp data the CRU crew uses to “prove” CO2-based AGW then it could prove useful, and welcome.
Weather update: More global warming falling in Central PA. And this theory is predicting a 50 year cooling phase? I might have to invest in a “global warming machine” to get groceries. Maybe some global warming shoes as well.

Pamela Gray
December 22, 2009 10:27 am

I am skeptical of anyone who uses wiggle matching without mechanism.

rbateman
December 22, 2009 10:28 am

No one knows what the heck is going on with climate.
Oh, that’s easy. Just step outside on a daily basis for at least 30 years.
And, if you’re living in most of the USA, you can feel it when you drive it as your SUV careens towards the nearest snow-encrusted ditch.

edward
December 22, 2009 10:29 am

Ray
The science is settled anew and its now CFC’s/Cosmic Rays.
Join the new ” Cosmic Ray Concensus” or you will be labeled a denialist and compared to Hitler.
Shiny
Edward

Editor
December 22, 2009 10:29 am

This was a career-ending paper.

Ray
December 22, 2009 10:31 am

““Most remarkably, the total amount of CFCs, ozone-depleting molecules that are well-known greenhouse gases, has decreased around 2000,” Lu said.”
Well, according to that chart from NOAA, the peek CFC concentration was around 1994. By the year 2000, it was down by 5% of the peak. Is his AGW mechanism delayed?
http://upload.wikimedia.org/wikipedia/commons/1/16/Ozone_cfc_trends.png

Michael
December 22, 2009 10:32 am

Here’s a look at the Sun in a very large graphic. Looks like just a few specks to me. Click on “Continuum” at this site.
http://www.solarcycle24.com/

December 22, 2009 10:33 am

Enduser (10:03:02)
As I recall, the ozone-warming theory originated with Kelly Bundy for the purpose of winning the beauty contest in Married With Children, Spring Break II. While the theory might not have undergone strict peer-review, it is cited frequently by eminent climate-scientists to explain “the anomalous cooling of Antarctica”. As with most theories of these eminent scientists, it is invertible.

Mark
December 22, 2009 10:34 am

Interesting that the sun plays a role in ozone depletion:
“Solar Blast From The Past Dwarfed Modern Ozone Destruction
ScienceDaily (Mar. 29, 2007) — A burst of protons from the Sun in 1859 destroyed several times more ozone in Earth’s atmosphere than did a 1989 solar flare that was the strongest ever monitored by satellite, a new analysis finds.
When energetic protons from the Sun penetrate Earth’s stratosphere, they ionize and dissociate nitrogen and oxygen molecules, which then form ozone-depleting nitrogen oxides.”
http://www.sciencedaily.com/releases/2007/03/070322105700.htm
“”Raining” Electrons Contribute To Ozone Destruction
ScienceDaily (Dec. 15, 2000) — First-time evidence shows electrons precipitating or ‘raining’ from Earth’s magnetosphere are destroying ozone in the upper atmosphere.
Scientists involved in the study of Solar-Atmospheric Coupling by Electrons (SOLACE) will report on this finding at the Fall American Geophysical Union (AGU) meeting in San Francisco, December 15-19, 2000. They have determined that this coupling can create a significant amount of nitrogen oxides highlighting a new aspect of natural ozone destruction.”
http://www.sciencedaily.com/releases/2000/12/001215082423.htm
“Ozone Layer Burned by Cosmic Rays
NASA satelliteCosmic conspiracy. Cosmic rays could be a major contributor to ozone destruction over Antarctica.
Cosmic rays may be enlarging the hole in the ozone layer, according to a study appearing in the 13 August print issue of PRL.”
http://focus.aps.org/story/v8/st8

Polar Bears and BBQ Sauce
December 22, 2009 10:36 am

OT,
Someone’s been teasing those guys over on Al Gore’s website:
http://www.repoweramerica.org/wall/#/view/49001
…shameful…. 🙂
[Link does not work]

edward
December 22, 2009 10:38 am

Let me be the first to establish the Cosmic Ray Credits market. All Galactics Cosmic Ray emitters will be forced to pay a tax on their Cosmic Ray emissions that target this quadrant of the galaxy. They will of course be allowed to purchase Cosmic Ray offsets by lowering their CR emissions to other parts of the galaxy.
Too late! I just got word that Rajendra Pachauri and Al Gore have partnered to innovate this market along with a consortium of Green companies.
Shiny
Ed

SandyInDerby
December 22, 2009 10:39 am

Enduser (10:03:02) :
I recently read that the ozone hole was responsible for the anomalous cooling of Antarctica. Now this guy says that the ozone hole is responsible for warming.
No one knows what the heck is going on with climate.
Hear hear

Robinson
December 22, 2009 10:39 am

I recently read that the ozone hole was responsible for the anomalous cooling of Antarctica. Now this guy says that the ozone hole is responsible for warming.

The abstract says:

The cosmic-ray driven electron-induced reaction of halogenated molecules adsorbed on ice surfaces has been proposed as a new mechanism for the formation of the polar ozone hole. Here, experimental findings of dissociative electron transfer reactions of halogenated molecules on ice surfaces in electron-stimulated desorption, electron trapping and femtosecond time-resolved laser spectroscopic measurements are reviewed. It is followed by a review of the evidence from recent satellite observations of this new mechanism for the Antarctic ozone hole, and all other possible physical mechanisms are discussed. Moreover, new observations of the 11 year cyclic variations of both polar ozone loss and stratospheric cooling and the seasonal variations of CFCs and CH4 in the polar stratosphere are presented, and quantitative predictions of the Antarctic ozone hole in the future are given. Finally, new observation of the effects of CFCs and cosmic-ray driven ozone depletion on global climate change is also presented and discussed.

and his previous paper showing an ozone/cosmic ray link said:

This Letter reports reliable satellite data in the period of 1980–2007 covering two full 11-yr cosmic ray (CR) cycles, clearly showing the correlation between CRs and ozone depletion, especially the polar ozone loss (hole) over Antarctica. The results provide strong evidence of the physical mechanism that the CR-driven electron-induced reaction of halogenated molecules plays the dominant role in causing the ozone hole. Moreover, this mechanism predicts one of the severest ozone losses in 2008–2009 and probably another large hole around 2019–2020, according to the 11-yr CR cycle.

Interestingly, on the NASA website (ask an astrophysicist) says:

Note added in 2001 August: It is thought that man-made chlorofluorocarbons (CFCs), such as Freon, are the major destroyer of the ozone layer. The prevailing theory is that ultraviolet light breaks down CFCs, releasing active chlorine, which destroys ozone molecules. However, a recent study suggests that cosmic rays may also break down CFCs. If this is correct, cosmic rays do play a part in creating ozone holes, but only because there are man-made CFC molecules for them to break down.

But that note, as it says, is added a good 8 years ago.

December 22, 2009 10:43 am

Icarus (10:10:01)
The satellite record shows a warming of 0.13 C per decade from 1979 to 2009, and cooling since 1998. Of course, both trends are statistically insignificant.

Robert Wood
December 22, 2009 10:44 am

Sounds along the lines of Svensmark. Forget about the “hole in the ozone”. It’s been there as long as we’ve observed and is probably a natural feature.

DirkH
December 22, 2009 10:44 am

“johnh (10:24:30) :
[…]
Its have your cake and eat it, global warming causes the hole but the hole causes cooling.
Well that sort of tortured logic just about says it all”
That’s not tortured logic, John – it would altogether be a system with a negative feedback. And systems with a negative feedback always reach an equilibrium. The AGW crowd loves to hypothesize about positive feedbacks that would lead to runaway effects thus causing the catastophy but the very existence of earth as an inhabitable planet is prove enough that there must be negative feedbacks that stabilize the climate. Granted, it might go up and down a little but it’s always rolling back into a local minimum. Get familiar with control circuits i would suggest.

DocMartyn
December 22, 2009 10:46 am

O.K. Here goes. CR going through the atmosphere cause the release of free electrons. These can recharge (inert to Ozone) halogen species, such as CFC, HCFC, HCl or ClONO2 into Cl- or Cl2. These species are photolyzed by uv light generating Cl atoms (that is chlorine radical). Chlorine radicals attack ozone and generate the oxychlorine radical that also attacks ozone, giving the catalytic cycle.
Cl(.) + O3-> OCl(.) + O2
OCl(.) + O3 -> Cl(.) + 2 O2.
So cosmic rays increase the amount of photolyzable chlorine’s. So an increase in CR = increase in Cl(.) and so O3 goes down
Implication of a drop in ozone. The top of the atmosphere cools, as less IR and uv is absorbed by ozone is absorbed.
The lower atmosphere warms up as more IR/uv gets through the ozone layers.
Result. CFC’s potentate the effects of CR’s in causing a differential temperature gradient in the atmosphere.
Low CR mean low Cl(.) means more O3 and low Earth temp (but higher stratosphere temps); but high CR means more Cl(.), less O3=Global warmins (stratosphere cooling).
These effects will continue until all the CFC have gone; which is about 60 years with a t1/2 of about a decade.

SteveSadlov
December 22, 2009 10:47 am

This is a very striking synthesis of Svensmark and earlier theories about CFC chemistry in the polar vortices. Now we’re getting somewhere.

Monroe
December 22, 2009 10:50 am

It seems we are all within the vast universe of Climate Science. The old school resists new ideas and change because they threaten egos and careers. But darn those new planets and galaxies just keep poping up.
Toques off to Professor Lu

latitude
December 22, 2009 10:51 am

use more hair spray

astonerii
December 22, 2009 10:55 am

If I am not mistaken, when the sun is strongest, cosmic rays are weakest. So explain how the strongest sun in centuries allowed significant enough cosmic rays to affect the CFCs and thus the Ozone and finally the temperature. Sounds fishy if you ask me. It may be in a journal, but it just does not jive. It is about as likely as doubling CO2 will result in 11C warming.
REPLY – TSI is strong, but solar wind is weak. It’s solar wind that affects cosmic rays. ~ Evan]

Dave F
December 22, 2009 10:56 am

Mark (10:34:25) :
I find that first article pertinent. Also, from that article, how they determined how much of the ozone layer was destroyed:
“Models using this energy total showed that 3.5 times more ozone was destroyed in the 1859 episode than in that of 1989.”
Shouldn’t be too hard to prove given that they observed the burst in 1989, but this is interesting because perhaps CFCs augment the depletion process wrt solar flares? Perhaps that blast in 1859 wasn’t nearly as effective as they modeled it to be?