One day later: Mauna Loa CO2 graph changes

UPDATE: 08/07 2:PM PST MLO responds with improvements to the CO2 data reporting

Approximately 24 hours after I published my story on the January to July trend reversal of CO2 at Mauna Loa, the monthly mean graph that is displayed on the NOAA web page for Mauna Loa Observatory has changed. I’ve setup a blink comparator to show what has occurred:

For those who don’t know, a blink comparator is an animated GIF image with a 1 second delay consisting only of the two original images from NOAA MLO. Individual image URLS for: August 3rd ML CO2 graph | August 4th CO2 Graph

Now the there is no longer the dip I saw yesterday. Oddly the MLO CO2 dataset available by FTP still shows the timestamp from yesterday: File Creation:  Sun Aug  3 02:55:42 2008, and the July monthly mean value is unchanged in it to reflect the change on the graph.

[UPDATE: a few minutes after I posted this entry, the data changed at the FTP site] here is the new data for 2008:

#               decimal          mean    interpolated    trend

#               date                                                 (season corr)

2008   1    2008.042      385.37      385.37      385.18

2008   2    2008.125      385.69      385.69      384.77

2008   3    2008.208      385.94      385.94      384.50

2008   4    2008.292      387.21      387.21      384.46

2008   5    2008.375      388.47      388.47      385.46

2008   6    2008.458      387.87      387.87      385.51

2008   7    2008.542      385.60      385.60      385.25

and here is the 2008 data from Sunday, August 3rd:

2008   1    2008.042      385.35      385.35      385.11

2008   2    2008.125      385.70      385.70      384.85

2008   3    2008.208      385.92      385.92      384.38

2008   4    2008.292      387.21      387.21      384.59

2008   5    2008.375      388.48      388.48      385.33

2008   6    2008.458      387.99      387.99      385.76

2008   7    2008.542      384.93      384.93      384.54

Here is the MLO data file I saved yesterday (text converted to PDF) from their FTP site.

Here is the URL for the current data FTP:

ftp://ftp.cmdl.noaa.gov/ccg/co2/trends/co2_mm_mlo.txt

I have put in a query to Pieter Tans, the contact listed in the data file, asking for an explanation and  change log if one exists.

UPDATE 08/05 8:55AM PST I have received a response from MLO:

Anthony,

We appreciate your interest in the CO2 data.  The reason was simply that

we had a problem with the equipment for the first half of July, with the

result that the earlier monthly average consisted of only the last 10

days.  Since CO2 always goes down fast during July the monthly average

came out low.  I have now changed the program to take this effect into

account, and adjusting back to the middle of the month using the

multi-year average seasonal cycle.  This change also affected the entire

record because there are missing days here and there.  The other

adjustments were minor, typically less than 0.1 ppm.

Best regards,

Pieter Tans

UPDATE 08/05 4:03PM PST

I have been in dialog with Dr. Tans at MLO through the day and I’m now satisfied as to what has occurred and why.  Look for a follow-up post on the subject. – Anthony

UPDATE 08/06 3:00PM PST

A post-mortem of the Mauna Loa issue has been posted here:

http://wattsupwiththat.wordpress.com/2008/08/06/post-mortem-on-the-mauna-loa-co2-data-eruption/

– Anthony

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August 6, 2008 8:15 am

Joy,
On my explanation page I have the two graphs of raw data for 2004: with and without outliers. Most outliers were to the low side (due to upslope winds, some 4 ppmv below average). That was a year with few days with volcanic outgassing. 1984 e.g. was a year with many days of high outliers due to volcanic outgassing (peaks of +20 ppmv). Both outliers are not used for daily, monthly and yearly averages, but still are available in the raw hourly averages data file.
I suppose that they simply have an automatic update of the monthly data, with as only algorithm that there must be at least 10 days of valid data. What they probably never had encountered is that if these 10 days were all at the end (or the beginning) of a month, this might give a bias in months with a huge seasonal trend…

Mike Bryant
August 6, 2008 8:34 am

This Mauna Loa thing has legs, around 350 comments in a couple of days.
Mike Bryant

August 6, 2008 8:54 am

Perhaps I’m naive, but they could have avoided this whole kerfluffle by simply posting an explanatory statement along with the altered graph. Any looming questions would then have been answered up front.
Oh well, live and learn….

August 6, 2008 9:06 am

Dave H,
On my explanation page I have some remarks about the influence of anthro 13C-depleted fossil fuel use (see the message to crosspatch) as fingerprint in the atmosphere. A nice introduction in the 13C cycle is made by Anton Uriarte Cantolla:
http://homepage.mac.com/uriarte/carbon13.html
A lot of ocean CO2 data can be found at:
http://cdiac.ornl.gov/oceans/home.html
Their publications are of interest.
More links (but several need an expensive subscription or payment by article):
http://www.aoml.noaa.gov/ocd/gcc/co2research/
http://www.sciencemag.org/cgi/content/full/298/5602/2374
http://www.atmos.colostate.edu/~nikki/Metzl-Lenton-SOLAS_China07.pdf
http://ioc.unesco.org/IOCCP/pCO2_workshop/Presentations/metzl-SOCOVV-Final2.pps
http://www.atmos.ucla.edu/~gruber/publication/pdf_files/gruber_thesea_02.pdf
http://www.agu.org/pubs/crossref/2002/2001GC000264.shtml
of particular interest (and free!):
http://www.pmel.noaa.gov/pubs/outstand/feel2331/abstract.shtml
That Barrow is leading Mauna Loa has two reasons: Barrow represents the atmosphere at ground level (and not so far from tundra, with a short but intensive summer season), where most of the processes of exchange take place. That is exchange with the oceans (more uptake in winter, more release in summer) and vegetation (the opposite of the oceans). The horizontal mixing is quite rapid (a matter of hours to days), but vertical mixing takes more time (days to weeks). As Mauna Loa is at 3,000 m, this gives a delay and a smoothing of the seasonal amplitude.

Fred . . .
August 6, 2008 9:35 am

John McDonald has nailed it . . .
“Dr. Tans data is being used to support a massive attempt to regulate our lives and potentially cost us all a huge drop in our standard of living – so his data manipulation with no peer review, within 24 hours, no documentation, no impact study, etc. tells me they are NOT a serious science organization”
Indeed. And how many other changes have been made that we don’t know about ??
Scientific organization ? I think not.
Very Mickey Mouse Operation with potentially tragic economic consequences.

Ken Westerman
August 6, 2008 9:37 am

As much fun as it is in keeping the climate mob down, one has to wonder if it is something worth fighting for in the long run.
I would say…let the government have their childish playtime with global warming and everything included (such as CO2 graphs)…and let them be taught a lesson in years to come: when global temperatures cool so on and so forth.
As for the folks at Real Climate, I tried to post this today. I think it sums up a lot of people’s feelings about their site.

Ken Westerman
August 6, 2008 9:37 am
Ken Westerman
August 6, 2008 9:39 am

Eh nevermind. Doesn’t wanna work. Not sure why. Oh well. Sorry for the triple post.
REPLY: Try pasting into notepad to remove formatting, then copy/paste into comment form. – Anthony

August 6, 2008 10:19 am

Been following your posts. Surprised at the number of individuals you have gathered in such a short time.
You’ve actually hit upon a subject matter that ties opinion to facts. Not to mention credible sources.

Kim Mackey
August 6, 2008 10:25 am

Dee Norris and Ferdinand Engelbeen,
Thanks for your excellent posts. They go a long way in helping to explain what happened, why, and what the importance or non-importance of this particular event was.
Kim

niteowl
August 6, 2008 10:36 am

Simmons:
It’s just the MS Excel Chart function plotting data series from spreadsheet columns. Then do a “Save as Web Page”, and it generates the charts as .GIFs.
General Question:
About the issue of constantly-rising CO2 concentrations; what were global temperatures doing 800 to 1200 years ago? Wouldn’t the lag in CO2 response to temperature changes observed in ice-core samples still be happening now, or has something happened to change all that? Are we seeing minor fluctuations from current conditions against a stronger response to a background signal from long ago? I sure don’t have an answer.

Fernando Mafili ( in Brazil)
August 6, 2008 11:12 am

Ferdinand Engelbeen:
Thanks by link; concentration of oxygen in the atmosphere. I really did not expect that the concentration of O2 were rising.
many chopps

Peter
August 6, 2008 12:22 pm

Ferdinand Engelbeen:
“the mass balance: more CO2 is emitted by humans than is accumulating in the atmosphere. That means that natural sinks (over a year) are larger than natural sources.”
I’m a bit confused by this. The consensus, amongst some, seems to be that around half of anthropogenic CO2 is absorbed by natural sinks.
But what then maintained CO2 levels before mankind started burning fossil fuels? Going by the above, one would expect that the downward slope in atmospheric CO2 would have been around the same slope (except in a negative direction), and a few hundred years of that would have resulted in little or no atmospheric CO2. This would probably have resulted in a large-scale dying-off of plants, which would in turn offset the decline in CO2 by a small amount (given that the oceans are the largest CO2 sinks)
Is there any evidence of such an event?
And, even if this did happen, how did CO2 levels recover?

Craig D. Lattig
August 6, 2008 12:42 pm

niteowl-very interesting graphs…thank you!
This thread certainly has me looking forward to the data we will be getting in the next few months….
OK, I’m convinced…Dr. Tan certainly works on top of a volcano and out in the Pacific…anyone else would have noticed that current data releases are instantly subject to reveiw by highly qualified individuals…my heart goes out to him…live and learn….
Craig

August 6, 2008 12:44 pm

Fernando,
There is some misunderstanding here: the level of oxygen is reducing, due to burning fossil fuels. The reduction can be calculated, as the amounts and types of fossil fuel which were burned are more or less known, thanks to the tax/sales inventories of many countries (there may be some underestimating due to illegal sales…). But the reduction of oxygen was slightly less than expected. This points to vegetation growth which was higher than vegetation decay over the last decade of the past century. As vegetation growth produces oxygen (and uses by preference the lighter kind of carbon, 12C), the difference between expected and measured oxygen in the atmosphere is what vegetation growth minus decay has net produced and thus is proportional to the amount of CO2 that is netto incorporated into vegetation. That amount is around 1.5 GtC/year which is going extra into vegetation.
The other point is that the incorporation of the lighter carbon isotope in growing vegetation increases the heavier 13C in the atmosphere, thus vegetation decay is not the cause of the declining levels of d13C in the atmosphere and upper oceans of the past 150 years.
Battle e.a. in Science used the O2 and 13C decline independent of each other to calculate how much CO2 was absorbed by the oceans and how much by vegetation for the period 1990-1997. Unfortunately there is no recent update of that article. See:
http://www.sciencemag.org/cgi/content/abstract/287/5462/2467

Mike Bryant
August 6, 2008 12:54 pm

“The consensus…seems to be that around half of anthropogenic CO2 is absorbed by natural sinks. But what then maintained CO2 levels before mankind started burning fossil fuels? Going by the above, one would expect that the downward slope in atmospheric CO2 would have been around the same slope (except in a negative direction), and a few hundred years of that would have resulted in little or no atmospheric CO2.”-Peter
Very insightful…

Ken Westerman
August 6, 2008 12:58 pm

niteowl:
In longer time scales, it appears that CO2 lags behind temperatures by ~800 years. Did we see warming in 1208 AD? If you believe in the MWP, then that sounds reasonable. However, with emissions today, it is probably difficult to know how much is from lag in temperatures. Someone who is better educated in respect to such things might be able to know the difference.

Stan Needham
August 6, 2008 1:15 pm

Ferdinand,
I learned a great deal the last time you visited, so I’m hoping you have the answer to a question that Evan Jones and I were discussing off-blog after your last visit. If human activity has played a significant role in the increasing level of atmospheric CO2 in the last 150 years, what explains the dip in CO2 during in the mid 1940’s when the manufacturing economies of the Allied and Axis powers were ramped up on a war-time footing, 2 medium sized Japanese cities were vaporized, much of Germany was incinerated in firestorms, and an incredible amount of ordinance was expended in a relatively brief period of time. Surely by your logic, CO2 should have seen a spike, not a dip.

August 6, 2008 1:46 pm

@Stan:
I suspect that CO2 output during WW2 was well below current anthropogenic levels.
However, aerosol output would have been rather high which might have well effected global temperatures but would require additional data to qualify exactly.
(Note the weasel words in that last sentence. It means I don’t really know and I need more grant $$$$ to maybe find out!)

Joy
August 6, 2008 1:58 pm

If the 800 to 1000 year CO2 lag is credible then this is precisely the sort of signal one would expect. Furthermore, surely it’s not just CO2 that will be released from the ocean in a warming world. Do we have such detailed analysis of other gasses and their trends over the geological timeframe? If CO2 is seen to be doing something different from all the other gasses then I might be inclined to believe this could be a human signal but that assumes that the figures for the carbon cycle are correct.
I’m still not convinced by the notion that scientists can calculate how much CO2 comes from volcanism, humans, warming oceans, decay, fungi altogether let alone break these figures down with any sort of useful precision. This probably makes me unusual even amongst sceptics. I’m open to being convinced though. What are the margins of error around the carbon sources and sinks?

August 6, 2008 2:01 pm

John McDonald and Fred,
I shouldn’t say that the Mauna Loa measurements (and for that matter a lot of other CO2 measurements all over the world) don’t have a rigourous quality assurance. Most of it is done automatically, like flagging outliers and calculating averages. Later on, more manual control is done and obvious errors are corrected. Discarding outliers from a trend is done frequently even in process control: if you react on all incoming data from a process, including outliers, one can run into deep trouble…
Flagging outliers is a part of quality control, as we are interested in more or less global averages and trends, not in local volcanic outgassing, local sugarcane field CO2 use or data from failing equipment. Local CO2 in vegetation (or volcanoes) may be of interest for biologists and scientists who want to study the carbon cycle in more detail, but there are better places to do that: midst the fields and/or forests, where some 400+ stations over the world are at work, or at the mouth of fumaroles…
If there is one data series in this world where I am pretty sure that the highest standards of data integrity and quality are maintained, then it is the CO2 data from Mauna Loa and the other 9 stations from near the North Pole to the South Pole. You should read the struggle of Dr. Charles D. Keeling to maintain quality of, and the continuous measurements at, Mauna Loa and other places against the different administrations. It really is a fascinating story:
http://scrippsco2.ucsd.edu/publications/keeling_autobiography.pdf
About the use of the Mauna Loa data: even if it is quite sure that humans are responsible for the increase in CO2, that doesn’t tell anything about the influence of the extra CO2 on temperature. That is where we differ from the AGW folks…

Stan Needham
August 6, 2008 2:28 pm

I suspect that CO2 output during WW2 was well below current anthropogenic levels.
I wouldn’t disagree, Dee, but clearly WW2 should have resulted in a measurable increase in anthropogenic CO2 compared to the years both immediately before and after. Instead, every ice core CO2 chart I’ve seen for that period shows a dip around 1943-45. Aerosol output might very well have masked any change in global temperatures, but I don’t see how they would have altered the CO2 level.

CAS
August 6, 2008 2:37 pm

Has it been noticed that the updated trend now shows three months in row for decline in the trendline? Isn’t that the first time as I thought previously there had never been more than two?

August 6, 2008 2:48 pm

In my humble opinion,
Mike Bryant’s comments so far are possibly the most concise and important questioning as of yet.
namely,

1) How many times in the past have these adjustment algorithms been run?
How long has Dr. Pieter Tan been responsible for adjustments?
2) Did his predecessor instruct in the necessity of these wholesale adjustments?
Are there any records of previous adjustments?
3) Did Dr. Keeling initiate a protocol that required regular adjustments? ”
Aaaarh Keeling, Mauna loa and it has to be said again,
Vostock, of course there is no mixing of data sets..
But where is the raw data, will we ever, ever see it.
Probably not, for the newbies to this particular “topic” here’s a link I hope explains and expands what is really being discussed here.
http://www.rocketscientistsjournal.com/2006/10/co2_acquittal.html#more
I apologise, it is a long, long article / paper, but the comments that follow are even better,
and may well explain / expand what the importance of and the probable inaccuracies in the Mauna Loa data set in it’s raw form are and why…
There is also another thread at the site with Gavin Schmidt’s reponses, and Dr Glassman’s replies….A great/ must read.
I think it is all too obvious that there almost certainly must already be a history of “adjustments” and mixing of data,
probably as obvious as a certain other Mann…
If ever the raw data is released, (but my last penny says it will never be willingly released) we’ll see…
Good science, not in my books, but hey I’m only a layman.
(and a tax payer)………………

August 6, 2008 3:01 pm

@Stan:
If current anthropogenic CO2 is 3% of the increase, what percent would it have been in 1944/45? I don’t think we would be able to distinguish it from the seasonal noise, warming oceans, etc…
:
The raw data is available from 1974 to 2006 as I posted earlier.
ftp://ftp.cmdl.noaa.gov/ccg/co2/in-situ/mlo/
ftp://ftp.cmdl.noaa.gov/ccg/co2/in-situ/README_insitu_co2.html
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