
Reposted from Jennifer Marohasy
The Available Evidence Does Not Support Fossil Fuels as the Source of Increasing Concentrations of Atmospheric Carbon Dioxide (Part 1)
Because the increase in the concentration of atmospheric carbon dioxide has correlated with an increase in the use of fossil fuels, causation has been assumed.
Tom Quirk has tested this assumption including through an analysis of the time delay between northern and southern hemisphere variations in carbon dioxide. In a new paper in the journal Energy and Environment he writes:
“Over the last 20 years substantial amounts of CO2 derived from fossil fuel have been released into the atmosphere. This has moved from 5.0 gigatonnes of carbon in 1980 to 6.2 gigatonnes in 1990 to 7.0 gigatonnes in 2000… Over 95% of this CO2 has been released in the Northern Hemisphere…
“A tracer for CO2 transport from the Northern Hemisphere to the Southern Hemisphere was provided by 14C created by nuclear weapons testing in the 1950’s and 1960’s.The analysis of 14C in atmospheric CO2 showed that it took some years for exchanges of CO2 between the hemispheres before the 14C was uniformly distributed…
“If 75% of CO2 from fossil fuel is emitted north of latitude 30 then some time lag might be expected due to the sharp year-to-year variations in the estimated amounts left in the atmosphere. A simple model, following the example of the 14Cdata with a one year mixing time, would suggest a delay of 6 months for CO2 changes in concentration in the Northern Hemisphere to appear in the Southern Hemisphere.
“A correlation plot of …year on year differences of monthly measurements at Mauna Loa against those at the South Pole [shows]… the time difference is positive when the South Pole data leads the Mauna Loa data. Any negative bias (asymmetry in the plot) would indicate a delayed arrival of CO2 in the Southern Hemisphere.
“There does not appear to be any time difference between the hemispheres. This suggests that the annual increases [in atmospheric carbon dioxide] may be coming from a global or equatorial source.”
********************
Notes
‘Sources and Sinks of Carbon Dioxide’, by Tom Quirk, Energy and Environment, Volume 20, pages 103-119. http://www.multi-science.co.uk/ee.htm
The abstract reads:
THE conventional representation of the impact on the atmosphere of the use of fossil fuels is to state that the annual increases in concentration of CO2 come from fossil fuels and the balance of some 50% of fossil fuel CO2 is absorbed in the oceans or on land by physical and chemical processes. An examination of the data from: i) measurements of the fractionation of CO2 by way of Carbon-12 and Carbon-13 isotopes; ii) the seasonal variations of the concentration of CO2 in the Northern Hemisphere; and iii) the time delay between Northern and Southern Hemisphere variations in CO2, raises questions about the conventional explanation of the source of increased atmospheric CO2. The results suggest that El Nino and the Southern Oscillation events produce major changes in the carbon isotope ratio in the atmosphere. This does not favour the continuous increase of CO2 from the use of fossil fuels as the source of isotope ratio changes. The constancy of seasonal variations in CO2 and the lack of time delays between the hemispheres suggest that fossil fuel derived CO2 is almost totally absorbed locally in the year it is emitted. This implies that natural variability of the climate is the prime cause of increasing CO2, not the emissions of CO2 from the use of fossil fuels.
Data drawn from the website http://cdiac.ornl.gov/trends/co2/contents.htm .
Tom Quirk has a Master of Science from the University of Melbourne and Master of Arts and Doctor of Philosophy from the University of Oxford. His early career was spent in the UK and USA as an experimental research physicist, a University Lecturer and Fellow of three Oxford Colleges.
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Laurence Kirk (17:30:00) :
“..Maybe in your back yard. But out here the wheat paddocks that replaced the evergreen eucalypt forest are bare dirt for seven months of the year, as there is negligible rainfall between October and April and the grounwater is mostly saline. (I don’t know, you city boys!)”
City-boy is only partly applicable to me, as I spent many summers and long weekends on a working farm/ranch in the U.S. south. Plus living and working abroad as I wrote above. We had to work very hard to keep the weeds out of the cultivated rows.
If deforestation has or had anything to do with increased CO2, then it sure does not show up in the annual cycle measured at Mauna Loa. From all the hysteria on the AGW side, one would think that the winter peaks in CO2 would be growing smaller or disappearing altogether. Peaks are still there, year after year. Like that battery bunny, still going, and going, and going…
Another AGW prediction that failed to materialize.
And the amount of specialty forests for pulp and paper, such as at Aracruz, where the cultivated trees grow many times faster than the native species, surely counter some of the deforestation. Aracruz’ eucalyptus trees are (at least in the 1980s when I was there) harvested every 7 years, having achieved a height of around 84 feet. They may have improved their trees in the past 25 years.
As I have written on this blog before, man’s planting and watering of millions of trees, shrubs, and many thousands of acres of grass just in Southern California alone are taking in CO2 by the ton every day. None of that was here before man settled and built up the southland area. Where is the AGW’ers applause for that one?
The same is true for the other cities/towns in the U.S. desert Southwest, Las Vegas, Salt Lake City, Phoenix, Tucson, El Paso, and others. One can fly over them in summer daylight, and see the green crop circles — absorbing CO2 by the ton, every day.
I have my doubts about that method of accounting unless they are also accounting for “non-consumptive” uses of fossil fuels.
For example crude oil turned into plastic which is now sequestered in land fills.
natural gas used to produce carbon black which is now sequestered in old tires, paints and pigments.
Not all fossil fuels are “burned” much of that fuel mass is simply changed to a different form without burning it.
A few years ago they were discussing what happens to all the rubber worn off of tires? If it there should be piles of the stuff built up beside the roads. As I recall they still are not completely confident about how it degrades and where all that carbon goes.
Larry
Pamela Gray (13:25:09) :
“Roger, it is called upwelling. The thermocline (the variably mixed water that sits on top of deeper, denser, colder water) is disturbed by wave action from trade winds and axial spin, thus allowing the more nutrient rich and colder underlayer water access to the top. Go here for a really good explanation.”
Thank you, Pamela. I read all of that in the links, slowly and with care, and I must ponder this for a while. It seems to me on first impression that this is horribly wrong. Winds, several hundred feet above the thermocline, and wave action also far removed (vertically), influence the cold water to upwell?
I suspect there is a much different mechanism at work, causing the undisputed upwellings of cold water where fishermen know to go to catch fish. One cannot deny that the cold water reaches the surface. I won’t speculate here (could be embarrassing to be really wrong) until I have looked into the physics of this just a bit more.
(Wanders off to the technical library, dusts off the physics books, the fluid dynamics books, physical chemistry book for properties of water, statics and dynamics and conservation of energy books, and settles in for a nice long read and contemplation…calculator and pencil and paper in hand for sketches and doodles…hoping my brain has not yet fossilized and I can understand this stuff that I once excelled at.)
This is one of the things I really like about WUWT. Thank you again, Anthony, for allowing me to play in your playground.
Pamela, you are a teacher? I feel like a student with an assignment…how do I submit my report for a grade?
hotrod,
“Not all fossil fuels are “burned” much of that fuel mass is simply changed to a different form without burning it.”
The amount of non-burned petroleum / natural gas is very small compared to the total of fossil fuels. When coal, oil, and natural gas are all accounted for, the amount of lube oils, petrochemical feedstocks (plastics and tires precursors), and asphalt are fairly small. In the U.S., these amount to roughly 5 percent of total petroleum consumed. The percent world-wide is even smaller, as the U.S. is different in the demands for petroleum products. So, figure around 1 percent max for world-wide un-burned fossil fuels.
http://tonto.eia.doe.gov/dnav/pet/pet_pnp_pct_dc_nus_pct_m.htm
has some data on the U.S. refinery yields.
Yes, Pamela is a teacher.
Winds, several hundred feet above the thermocline, and wave action also far removed (vertically), influence the cold water to upwell?
I suspect there is a much different mechanism at work
There is a considerable change of air pressure over the oceans. The NAO and NPO, for example, are atmospheric dipolar events that seriously affect both climate on land and Sea Surface Temperatures.
Ferdinand Engelbeen
2 points:
1. You attribute all of 4GtC to humans. Then you use this equation to prove that humans are responsible for extra 4Gt of carbon. Isn’t it a bit, well, circular?
2. If we use your line of reasoning, then without human emissions amount of CO2 would be constantly going down, causing global cooling (less CO2-lower temperature) until we either freeze to death of die of starvation (or both)?
I scanned through all postings to try and see if this is a duplication, I hope iut is not. I don’t understand what all the discussion is about. http://www.ipcc.ch/ipccreports/ar4-wg1.htm, Chapter 7, Figure 7.5 shows without any room for interpretation how the north-south gradient of CO2 has increased from 0.5ppm to close to 3ppm (that is the difference between annual mean concentrations (ppm) at Mauna Loa and the South Pole, Keeling and Whorf, 2005, updated) as fossil fuel emissions (GtC) increased from just under 3 to just over 7. A lock at the image at the top of the page, and just some visual integration and averaging of the north and south hemisphere seems completely consistent with that Fig7.5. There are more and redder patches in the north than in the south.
DJ Point taken (as a skeptic) . It is quite possible co2 rising due to human activity ( still has to be proved) there is nothing about it showing that it affects climate
Re Journals PNAS, Nature ect. “Leading Journal”, no longer counts. A major NEW discovery ie:, A novel Genetic finding in Nature would probably be credible, “Climate Science” to date not really at hot one for Nature (just see Steig’s Antarctic “warming” Debunking in all leading Science blogs run by Meteorologists or expert statistitians such as here or at CA. On the other hand I think “Climate Science” is something that should and needs to be pursued, although now its like a bunch of kids playing computer games… (imagine being able to forecast months ahead!). If climate scientist took this attitude now, their “science would eventually be recognized possibly.. LOL
Turns out there are two assumptions. The isolation of fossil fuels, and at what point of the sales chain is the data taken from? That is important.
The = sign is not correct either, as you attribute a value to something outside the equation, presumably to simplify the equation, but it does not necessarily equal if there is a value outside the equation that bears upon it.
George E. Smith (16:35:24) :
I’m sure there’s a way to look at it and know how much of each spevcies is in there by volume of course. Counting heads would do it; but that would be abundance by molecular species instead of volume.
I still say it is much easier to specify the relative numbers of molecules of each species present; and then that doesn’t matter whether the gases are ideal or not, or if there is water present.
The measurement is typically done by IR spectroscopy using wavelengths absorbed by the species of interest, water is removed for several reasons: being a variable component of air it is removed to give a common basis for comparison, being IR active it may absorb somewhat at the wavelength of interest, and last but certainly not least the optics and cells used in IR spectrometers are frequently made from salt crystals which prefer dry air!
Those MMGWCC folks are really determined to eliminate water from consideration in climate effects aren’t they.
Well when the models include water in its correct vapor, liquid and solid phases present at any time; I’ll start to pay some attention to what the climate models tell us happened years ago; even though we know from observations what that was.
Why do you think that water isn’t included in the models?
Notice in that July snapshot above that places that have a lot of ice and snow; such as Antarctica, Greenland, and the Himalaya ranges show a lot of low carbon blue.
Sort of gives you the idea that the original moisture in the air, that created those ice and snow fields in the first place dissolved a lot of CO2 (which is more soluble in colder water) and whisked it out of the air, upon precipitation.
It’s not just because of the ice and snow it’s also because they are high and cold (below -20ºC). CO2 is not soluble in ice.
Antarctic Bottom water, flowing over a riffle box several thousand k’s long, and at times with the riffles 2000 metres high (East Pacific Rise) may be dropping C14 (and C13?) preferentially in its travels. They are heavier than C12, after all. That will sink all isotope assumptions to date, when it surfaces as La Nina up-welling, as the released CO2 will look like it is as old as that from fossil fuel. Maybe.
Plant or phyto-plankton do one hell of a lot of photosynthesis. The geophysics prof at the University of Cape Town, Louis Ahrens, told some of us rookie students, in a short meeting in a corridor in 1970, “never mind the Amazon rainforest, for the real photosynthesis, watch the marine plankton.” He was the lad who did the moon rocks for NASA, and was president of the International Union of Geochemists and Cosmochemists ( I think it was) . So who were we to argue?
See the website for an alternative model to AGW, geomag-based, and a one-page sceptics starter kit, of just two matched maps, if bored.
The Church of the Holy Molecule is in trouble, methinks.
Hooroo,
Peter Ravenscroft
Another greenie geologist and AGW sceptic
Closeburn, Queensland
quote Pamela Gray (07:08:40) :
Damn! In that last sentence I meant to say ever increasing atmospheric CO2 in linear step to ever decreasing plankton blooms. I was in such an excited state! endquote
Aha, but you forgot to explain the isotope signal. There is more 12C in the atmosphere than expected, Man burns high 12C fuel, therefore Man has caused the high 12C signal in the atmosphere.
Or something else is happening.
Ferdinand Engelbeen (above) has an isotope graph which people claim proves an anthropic source for the light C. However, the graph does not actually do that — the light C signal begins around 1700 which is well before we started pumping oil. So, how to account for that?
There are two ends to the light isotope pipeline, production and consumption. If Man has altered the consumption end — something he has had the capacity for since large scale agriculture began — then it must be in the direction of a greater heavy isotope pull down.
Starving phytoplankton populations alter their balance to become more C4 metabolism oriented. C4 discriminates less than C3 metabolism and the resultant phyto incorporates more 13C. When it dies and sinks, it takes that 13C out of the atmosphere. The atmosphere is now relatively light in 13C, but foolishly we interpret this as being caused by an addition of 12C, not a reduction of 13C.
Diatoms bloom earlier than phytos, and they outcompete their slower rivals until they run out of dissolved silica to make their intricate and beautiful shells. Only when the diatoms have run out of silica can the phytos, making their calcium carbonate structures, begin to flourish.
Large scale agriculture will have been pushing a lot of dust into the oceans and been addng silica. Thus, from much earlier than the approved text would have us believe, more diatoms. Diatoms — tahdah! — use a C4-like carbon fixation process which pulls down more 13C and pumps it into the deep ocean. The heavy C component in the atmosphere goes down, hence Mr Engelbeen’s graph, falling since 1700AD.
I’ve thought of.. I think it’s four ways that we could have disrupted 12C/13C balance. I think that all four are probably involved in the anthropic signal.
Someone above (excuse my not checking, it’s four in the morning and I only came down for a cup of tea) mentioned WWII and the climate signal there. I’d love to see a really detailed breakdown of the isotope signal from ’38 to ’50. The whole period is very interesting, with the most intriguing data being the UKMO marine air temperature anomaly MOHMAT 4.3. This doesn’t smear out the initial warming (the smear in Hadcrut is a function of the IMHO dubious Folland and Parker bucket correction) or mask the precipitous drop once the Kriegesmarine had stopped covering the ocean surface with oil.
One of my explanations of the isotope drop involves low chromium and zinc levels — starved of these phytos go into their C4 mode — and there ought to be a jump in 12C levels when a really big volcano pumps high Cr and Zn leachate ash into the oceans.
Enough! I’m falling asleep.
JF
Google ‘the opal ocean’.
The Mohmat graph may be on Bob Tisdale’s site.
Have to admit, my first thought re. the “Gore Recants?” piece was to check the date on my computer, see if it had jumped to April First. I put the note in as a good skeptic, resolutely open either way but first impulse being to doubt, with the evidence I had at the time at my disposal.
Belatedly – thank you for this thread – it’s exactly the kind of evidence I need to reply to the “manmade carbon isotopes” AGW stuff, it’s going to be added to my Primer (click my name).
REpeating an old post from wattsup…
http://wattsupwiththat.com/2009/01/11/mauna-loa-co2-record-posts-smallest-yearly-gain-in-its-history/#comment-72540
Allan M R MacRae (04:01:04) :
Annualized Mauna Loa dCO2/dt averaged ~1ppm/year from 1958 to ~1978, then ~1.5 ppm/year from ~1978 to ~2001, then >2ppm/year from ~2001 to ~2006, and since then has dropped below 2ppm/year (consistent with strong global cooling since January 2007).
However humanmade CO2 emissions have continued to increase over the past few years, as they have every year over the past century or more. Why then is atmospheric dCO2/dt not also increasing?
Mauna Loa (and global) dCO2/dt correlates well with the Lower Troposphere temperature anomaly, but as I noted in my January 2008 paper*, CO2 lags temperature by ~9 months.
The impact of global temperature on atmospheric CO2 concentrations is apparent.
The impact of atmospheric CO2 concentration on global temperature is much more difficult to demonstrate, probably because it is insignificant.
Regards, Allan
_________________________
Annualized Mauna Loa dCO2/dt has “gone negative” a few times in the past (calculating dCO2/dt from monthly data, by taking CO2MonthX (year n+1) minus CO2MonthX (year n) to minimize the seasonal CO2 “sawtooth”.)
These 12-month periods are (Year-Month ending):
1959-8
1963-9
1964-5
1965-1
1965-5
1965-6
1971-4
1974-6
1974-8
1974-9
Has this not happened recently because of increased humanmade CO2 emissions, or because the world has, until recently, been getting warmer?
I noted in a paper published one year ago that dCO2/dt changes contemporaneously with “average” global temperature, and CO2 lags temperature by ~9 months.
* For those who are interested, my paper and spreadsheet are at:
http://icecap.us/index.php/go/joes-blog/carbon_dioxide_in_not_the_primary_cause_of_global_warming_the_future_can_no/
CO2 data from Mauna Loa:
ftp://ftp.cmdl.noaa.gov/ccg/co2/trends/co2_mm_mlo.txt
I like and respect Ferdinand, but am not at all convinced by his “material balance” argument.
Quoting Richard Courtney, who has often debated Ferdinand E on this subject:
The known facts of the matter are:
1.
The increase in atmospheric CO2 concentration each year is much less than the natural variations in atmospheric CO2 concentration within each year.
2.
The increase in atmospheric CO2 concentration over each year is the residual of the natural variations in atmospheric CO2 concentration within each year.
3.
The anthropogenic emission of CO2 each year is much less than the natural variation within each year.
4.
The change to the 12C:13C isotope ratio of atmospheric CO2 is in the direction expected if the recent increase in atmospheric CO2 concentration were caused by the anthropogenic emission of CO2.
But if the ratio changes then there is a 50:50 chance that it will change in that direction or the other.
5.
The magnitude of the change to the 12C:13C isotope ratio of atmospheric CO2 is much smaller than expected if the recent increase in atmospheric CO2 concentration were caused by the anthropogenic emission of CO2.
6.
The fact in point (5) indicates that most of the change to the 12C:13C isotope ratio of atmospheric CO2 and most of the recent increase in atmospheric CO2 concentration was caused by some unknown, natural (i.e. non-anthropogenic) effect.
7.
The fact in point (6) indicates that all of the change to the 12C:13C isotope ratio of atmospheric CO2 and all of the recent increase in atmospheric CO2 concentration may have been caused by the same unknown, natural (i.e. non-anthropogenic) effect.
Simply,
it is possible that none of the rise in atmospheric CO2 concentration and none of the change to the 13C:12C atmospheric isotope change were caused by anthropogenic emission
but were due to the unknown, natural (i.e. non-anthropogenic) effect that caused most of the change to the 12C:13C isotope ratio of atmospheric CO2.
8.
But the anthropogenic emission may have disturbed the carbon cycle such that the equilibrium state(s) of some parts of the carbon cycle have altered.
Therefore,
it is possible that all of the rise in atmospheric CO2 concentration and all of the change to the 13C:12C atmospheric isotope change were caused by the anthropogenic emission
that induced the unknown, natural (i.e. non-anthropogenic) effect that caused the observed change to the 12C:13C isotope ratio of atmospheric CO2.
9.
It is possible that both the effects noted in points 7 and 8 contributed to the change to the 12C:13C isotope ratio of atmospheric CO2 and to the recent increase in atmospheric CO2 concentration.
Therefore,
it is possible that some of the rise in atmospheric CO2 concentration and some of the change to the 13C:12C atmospheric isotope change were due to the anthropogenic emission.
10.
The change in atmospheric oxygen concentration in recent years is consistent with the amount of fossil fuel that was burned in those years.
In summation, the known facts (listed as points 1 to 10 above) demonstrate that
there is no conclusive evidence that any of the 20th century increase in atmospheric CO2 concentration is or is not due to the burning of fossil fuels.
PS to Roger Sowell (12:08:21) :
No offense meant re ‘City Boy’ comment! It was said in jest..
Best regards,
LK
Henry’s Law.
Roger Sowell (19:31:01) I would add to your list the whole front range of Colorado, which was nothing more than a few cottonwoods along a couple of rivers, some sparse pear cactus and sagebrush. What we have today is wholly from irrigation.
Roger Sowell (19:49:36, 3/25), thanks for your skepticism re upwelling/thermocline. I share the experience without any of the expertise. “Winds, several hundred feet above the thermocline, and wave action also far removed (vertically), influence the cold water to upwell?” I look forward to your report and your grade.
Also appreciation to Peter Ravenscroft for linking CO2 levels to the earth’s magnetic field (which is also related to the Sun’s activity in some way?), again, a connection I find in reading various scientific papers. And to Allen MacRae for his summary and paper — ST, LT, dCO2/dt and CO2 all have a common primary driver, and that is not humankind.” . And to Anthony, Jennifer Marohasy, and Tom Quirk. This essay and the comments have been a great read and have stimulated so many more questions — plus more knives in the heart of that vampiric AGW/Evil CO2.
I see that because of this thread, Lucy Skywalker is adding more to her primer, an excellent introduction for those just entering the scientist Van Helsing’s retinue. It has changed the minds of some engineer and scientist friends whose great efforts in their own fields do not leave them time to read outside the AGW takeover of the here-to-fore important scientific publications. (But they are hungry for the science, not for the blood of civilization.)
Upwelling is why the PDO anomaly has turned cold. Compare the vapor and cloud trajectories with the Pacific Ocean SST change and you will see the pattern. By the way, winds ARE near the surface, else sailing ships would be dead in the water.
Of note, our local paper has reported that a near record number of salmon have returned, leading to a possible salmon season on the Imnaha river. This near record number, along with high numbers of steal head returning to spawning grounds makes me think there are more nutrients in the Pacific and estuaries allowing these fish to survive in greater numbers. Could it be that we are having plankton blooms already? And will MLO pick this up in terms of a wiggle in CO2? Not likely. Its placement pretty much guarantees that it will measure whatever the trade wind blows its way. It cannot measure the increase sink that may be happening in a colder ocean. At least not for a while.
“imagine being able to forecast months ahead!”
These guys already do:
http://weatheraction.com/
They have a far better record than the supercomputer-equipped UK Met Office, who predicted a ‘mild winter’ in line with their general pitch about warming.
The don’t think much of AGW, either!
http://weatheraction.com/id4.html
Ferdinand
Thank you for replying. You say that “I hope I made it clear that I don’t assume that the natural sources and sinks are constant”.
Perhaps I oversimplified, but if they’re not constant, they must be tracking each other to satisfy your maths. Is that likely?
Imagine another future for Mauna Loa. It measures whether or not there is sufficient build-up of CO2 and dust to predict that with upwelling, the plankton bloom should be such and such, resulting in a marine food production increase of such and such. I say this because the location of that station is right where the natural oscillating cyclic trade wind supplies all the necessary ingredients for plankton growth: Wind, CO2 and dust. The CO2 is there. The wind has kicked up and caused an upwelling of cold, nutrient rich water. Now all we need are dryer, colder windier conditions over the African/Asian/South American continents to start producing dust that will seed both a cooler Atlantic and Pacific.
“”” Phil. (20:45:36) :
George E. Smith (16:35:24) :
I’m sure there’s a way to look at it and know how much of each spevcies is in there by volume of course. Counting heads would do it; but that would be abundance by molecular species instead of volume.
I still say it is much easier to specify the relative numbers of molecules of each species present; and then that doesn’t matter whether the gases are ideal or not, or if there is water present.
The measurement is typically done by IR spectroscopy using wavelengths absorbed by the species of interest, water is removed for several reasons: being a variable component of air it is removed to give a common basis for comparison, being IR active it may absorb somewhat at the wavelength of interest, and last but certainly not least the optics and cells used in IR spectrometers are frequently made from salt crystals which prefer dry air!
Those MMGWCC folks are really determined to eliminate water from consideration in climate effects aren’t they.
Well when the models include water in its correct vapor, liquid and solid phases present at any time; I’ll start to pay some attention to what the climate models tell us happened years ago; even though we know from observations what that was.
Why do you think that water isn’t included in the models? “””
Well Phil, I certainly did not mean to imply that the science of Quantitative Analysis is not an old hat part of Chemistry (which isn’t my forte).
My whole point is that since the discovery of molecules, and elements, it is much simpler to quantify mixtures on the basis of how many molecules of each species are present; well the ratios of those numbers anyway. Then there is no need to get involved in Ideal gas theory, or Van der Waal’s equation. Also the molecular abundances easily reveal that GHG trace gases are so rare in the atmosphere, that they act as individual molecules; and not in any collective way.
So it is not like Solid State Physics where the atoms act in concert, so that the bulk properties of the material are quite different from atomic properties.
I’m familiar with some of the problems of IR spectroscopy because of the problem with water damage to the optical elements.
As to this question:- “Why do you think that water isn’t included in the models? ”
I never said any such thing. I did say the following:- “Well when the models include water in its correct vapor, liquid and solid phases present at any time….”
If your information is that this has been accomplished; then that will be the first I have heard of the modelling community claiming to correctly model clouds in their GCMs. I’ve never heard any such claim before.
And given that we have no real way to even observe and measure the effect of clouds (in any scientifically accurate way); I doubt that the modellers have reduced to models, that which we cannot even obseve properly.
If you know of a network of ground, or satellite based cloud monitoring sensors, I would be happy to learn about it.
Satellite monitoring would have it’s limitations, being able to measure albedo effects; but not the ground level insolation under those clouds. And it would require a satellite network similar to the Iridium system to have complete global coverage 24/7.
And the ground network of temperature measuring stations, is already inadequate to do that task; and would fall far short of monitoing ground level insolation everywhere on earth 24/7.
But once again I am anxious to learn; so if you know of such networks can you point us to their data output.
Otherwise I will stick by my statement; which was different from your question.
George